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Crystal structure of novel R3Fe(Co, Ni)0.5SnS7 (R = Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy and Ho) compounds

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Abstract

The crystal structures of quaternary R3Fe0.5SnS7, R3Co0.5SnS7 and R3Ni0.5SnS7 (R = Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy and Ho) compounds of La3Mn0.5SiS7 structure type (space group P63, Pearson symbol hP23) were determined by X-ray single crystal and powder diffraction. R atoms occupy monocapped trigonal prisms; Fe(Co, Ni) atoms are located in octahedra, while Sn atoms are located in tetrahedra.

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Eastern European National University, Voli Ave 13, Lutsk, 43009, Ukraine

    Khrystyna Melnychuk & Oleg Marchuk

  2. Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna str. 2, P. O. Box 1410, 50-950, Wrocław, Poland

    Marek Daszkiewicz

  3. Department of Ecology and Protection of Environment, Eastern European National University, Voli Ave 13, Lutsk, 43009, Ukraine

    Lubomir Gulay

Authors
  1. Khrystyna Melnychuk
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  2. Oleg Marchuk
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  3. Marek Daszkiewicz
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  4. Lubomir Gulay
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Correspondence to Oleg Marchuk.

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Melnychuk, K., Marchuk, O., Daszkiewicz, M. et al. Crystal structure of novel R3Fe(Co, Ni)0.5SnS7 (R = Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy and Ho) compounds. Struct Chem 31, 1945–1957 (2020). https://doi.org/10.1007/s11224-020-01558-0

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  • DOI: https://doi.org/10.1007/s11224-020-01558-0

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