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Coexistence of two conformational isomeric chains in a zinc(II) phosphonate induced by π···π stacking interactions

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Abstract

Hydrothermal reaction of zinc acetate with diethyl [(phenylsulfonyl)methyl]phosphonate as well as 1,10-phenanthroline (phen) afforded a novel zinc(II) phosphonate with the formula of [Zn4(PhSO2CH2PO3)4(phen)2(H2O)2]·2H2O. Such compound features two conformational isomeric 1D chains which are regulated by two different π···π stacking interactions. In addition, it exhibits broad blue fluorescent emission band at 387 nm.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21061001) and the Natural Science Foundation of Jiangxi Provincial Education Department (No. GJJ10714).

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Authors and Affiliations

  1. Institute of Polymers, Nanchang University, Nanchang, 330031, People’s Republic of China

    Xiaokang Li & Yiwang Chen

  2. College of Chemistry and Life Science, Gannan Normal University, Ganzhou, 341000, People’s Republic of China

    Xiaokang Li, Yuhui Sun, Zhonggao Zhou & Ziyi Du

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  1. Xiaokang Li
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  2. Yuhui Sun
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  3. Yiwang Chen
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  4. Zhonggao Zhou
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  5. Ziyi Du
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Corresponding authors

Correspondence to Yiwang Chen or Ziyi Du.

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Li, X., Sun, Y., Chen, Y. et al. Coexistence of two conformational isomeric chains in a zinc(II) phosphonate induced by π···π stacking interactions. Struct Chem 23, 91–96 (2012). https://doi.org/10.1007/s11224-011-9852-6

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  • DOI: https://doi.org/10.1007/s11224-011-9852-6

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