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Experimental and theoretical studies on bis[μ-2-methoxy-N′-(2-oxidobenzoyl)benzohydrazidato(3-)]dipyridinetricopper(II)

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Abstract

A novel homotrinuclear pyridine Schiff base copper(II) compound, [Cu3(C15H11N2O4)2(C5H5N)2], has been synthesized and characterized by elemental analysis and X-ray single crystal deterimination. X-ray structural determination reveals that each copper(II) ion has a distorted square-planar geometry. The central copper ion is coordinated by two O and two N atoms from two Schiff base ligands, while each terminal copper ion is coordinated by one N and two O atoms of one Schiff base ligand and by one N atom of a pyridine molecule. Density funcational theory (DFT) method calculations of the structure, atomic charges distribution and natural bond orbital (NBO) analyses have been performed. The coordinate stabilization energies show that the trinuclear copper(II) compound is very stable.

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References

  1. Zhang Y, Guo ZJ, You XZ (2001) J Am Chem Soc 123:9378

    Article  CAS  Google Scholar 

  2. Downing RS, Urbach FL (1969) J Am Chem Soc 91:5977

    Article  CAS  Google Scholar 

  3. Ganeshpure PA, Tembe GL, Satish S (1996) J Mol Catal A 113:L423

    Article  CAS  Google Scholar 

  4. Bosnich B (1968) J Am Chem Soc 90:627

    Article  CAS  Google Scholar 

  5. Costes JP, Dominiguez-Vera JM, Laurent JP (1995) Polyhedron 14:2179

    Article  CAS  Google Scholar 

  6. Bruker (2002) SMART and SAINTPLUSE. Bruker AXS Inc., Madison, Wisconsin, USA

  7. Sheldrick GM (1996) SADABS. Program for empirical absorption correction of area detector. University of Göttingen, Germany

    Google Scholar 

  8. Sheldrick GM (1997). SHELXTL-97, Program for x-ray crystal structure solution. University of Göttingen, Germany

    Google Scholar 

  9. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Montgomery JA Jr, Vreven T, Kudin KN, Burant JC, Millam JM, Iyengar SS, Tomasi J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson GA, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox JE, Hratchian HP, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Ayala PY, Morokuma K, Voth GA, Salvador P, Dannenberg JJ, Zakrzewski VG, Dapprich S, Daniels AD, Strain MC, Farkas O, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Ortiz JV, Cui Q, Baboul AG, Clifford S, Cioslowski J, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin RL, Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Challacombe M, Gill PMW, Johnson B, Chen W, Wong MW, Gonzalez C, Pople JA (2004) Gaussian, Inc., Wallingford, CT

  10. Yu ZX, Sun YX (2006) Acta Cryst E62:m3521

    CAS  Google Scholar 

  11. ChemOffice software package (Version 8.0), CambridgeSoft Corporation, 2003

Download references

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Authors and Affiliations

  1. Department of Chemistry, Teachers College of Qingdao University, Qingdao, Shandong, 266071, P.R. China

    Qiang Liang & Qian Wang

  2. Department of Chemistry, Qufu Normal Univeristy, Qufu, 213165, P.R. China

    Shu-Fei Xu & Yu-Xi Sun

  3. Materials Chemistry Laboratory, Nanjing University of Science and Technology, Najing, 210094, P.R. China

    Yu-Xi Sun

Authors
  1. Qiang Liang
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  2. Qian Wang
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  3. Shu-Fei Xu
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  4. Yu-Xi Sun
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Correspondence to Qiang Liang.

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Liang, Q., Wang, Q., Xu, SF. et al. Experimental and theoretical studies on bis[μ-2-methoxy-N′-(2-oxidobenzoyl)benzohydrazidato(3-)]dipyridinetricopper(II). Struct Chem 19, 279–284 (2008). https://doi.org/10.1007/s11224-008-9283-1

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  • DOI: https://doi.org/10.1007/s11224-008-9283-1

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