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Two Zn(II) and one Mn(II) complexes using two different hydrazone ligands: spectroscopic studies and structural aspects

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Abstract

Three new coordination complexes of Zn(II) and Mn(II) have been synthesised using two different tridentate N,N,O donor hydrazone ligands, Hpbh and Hacpbh respectively. The complexes [Zn(pbh)2] (1) and [Zn(acpbh)2] (2) have been synthesized by the treatment of ZnSO4 · 7H2O with Hpbh and Hacpbh hydrazone ligands, respectively. The Mn(II) complex [Mn(acpbh)2] (3) was obtained on reacting Mn(NO3)2 · 4H2O with the ligand Hacpbh. The ligands Hpbh and Hacpbh were prepared by condensing pyridine-2-carboxaldehyde and 2-acetylpyridine with benzhydrazide respectively. Inspite of varying the carbonyl functionality attached to the pyridine moiety present in the hydrazone ligands in both the Schiff bases, we obtained three mononuclear complexes 1, 2, and 3 which were clearly characterized from single crystal X-ray diffraction studies. Spectroscopic investigations like IR and UV/Vis have been carried out for 1, 2, and 3. Fluorescence studies have been performed for 1 and 2. For 3 cyclic voltammetry, room temperature magnetic study and EPR measurements have been recorded.

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Acknowledgments

We sincerely acknowledge Department of Science and Technology, New Delhi, Govt. of India, for the financial support. We also acknowledge Dr. Andres Ibañez of University of Chile and Dr. Andrés Goeta of Durham University for performing the structural measurement of complex 3.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Kolkata, 700 032, West Bengal, India

    Aurkie Ray, Sambuddha Banerjee, Soma Sen & Samiran Mitra

  2. Department of Chemistry, Howard University, 2400 Sixth Street, NW, Washington, DC, 20059, USA

    Ray J. Butcher

  3. Department of Chemistry, School of Engineering and Physical Sciences, Heriot Watt University, Edinburgh, EH14 4AS, UK

    Georgina M. Rosair

  4. Depto de Físcia, Fac. De Ciencias Físicas y, Matemáticas and CIMAT, U. de Chile, Av. Blanco Enclada 2008, Santiago de Chile, Chile

    Maria T. Garland

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  1. Aurkie Ray
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Correspondence to Samiran Mitra.

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Ray, A., Banerjee, S., Sen, S. et al. Two Zn(II) and one Mn(II) complexes using two different hydrazone ligands: spectroscopic studies and structural aspects. Struct Chem 19, 209–217 (2008). https://doi.org/10.1007/s11224-007-9274-7

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  • DOI: https://doi.org/10.1007/s11224-007-9274-7

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