Skip to main content
SpringerLink
Log in

Paradigms and paradoxes: patterns and estimation of the entropy of formation of aqueous hydrogen containing mono and polynuclear oxyanions

  • Original paper
  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

“Simple” energetic patterns, where simple means the use of parameters derived only from the stoichiometry of these species, are relatively rarely discussed in the literature. In addition, entropy studies have been dominated by derivation of the absolute quantity S° rather than the entropy of formation (TΔf S o). Relationships between the entropy of formation and different parameters such as negative value of the charge of the species, the number of oxygen atoms, the natural logarithm of the molecular weight, the total number of atoms and the number of central atoms that are gases were recently discussed by us for aqueous polynuclear oxyanions. As shown here hydrogen containing anions do not follow this pattern. In this study, new approaches for the estimation of the entropy of formation of aqueous hydrogen containing mono and polynuclear oxyanions are suggested, evaluated and recommended.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ponikvar M, Liebman JF (2006) Struct Chem 17:623

    Article  CAS  Google Scholar 

  2. Wagman DD, Evans WH, Parker VB, Schumm RH, Halow I, Bailey SM, Churney KL, Nuttall RL (1982) The NBS tables of chemical thermodynamic properties: selected values for inorganic and C1 and C2 organic substances in SI units. J Phys Chem Ref Data 11(Supplement 2)

  3. Kren RM, Dodgen HW, Nyman CJ (1968) Inorg Chem 7:446

    Article  CAS  Google Scholar 

  4. Horner DA, Connick RE (1986) Inorg Chem 25:2417

    Article  Google Scholar 

  5. Poskrebyshev GA, Shafirovich V, Lymar SV (2004) J Am Chem Soc 126:891

    Article  CAS  Google Scholar 

  6. Larson JW (1991) Polyhedron 10:1695

    Article  CAS  Google Scholar 

  7. Vasil’ev VP, Shorokhova V, Ivanov I (1973) Zh Neorg Khim 18:305

    CAS  Google Scholar 

  8. Cruywagen JJ, Rohwer EFCH (1975) Inorg Chem 14:3136

    Article  CAS  Google Scholar 

  9. Larson JW (1995) J Chem Eng Data 40:1276

    Article  CAS  Google Scholar 

  10. Miller JC, Miller JN (2002) Statistics and chemometrics for analytical chemistry, 4th edn. Prentice Hall, Harlow, pp 141–145, 230–231

Download references

Author information

Authors and Affiliations

  1. Jožef Stefan Institute, Jamova 39, Ljubljana, 1000, Slovenia

    Maja Ponikvar

  2. Department of Chemistry and Biochemistry, University of Maryland, Baltimore County (UMBC), 1000 Hilltop Circle, Baltimore, MD, 21250, USA

    Joel F. Liebman

Authors
  1. Maja Ponikvar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Joel F. Liebman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Joel F. Liebman.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ponikvar, M., Liebman, J.F. Paradigms and paradoxes: patterns and estimation of the entropy of formation of aqueous hydrogen containing mono and polynuclear oxyanions. Struct Chem 18, 409–413 (2007). https://doi.org/10.1007/s11224-007-9160-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-007-9160-3

Keywords

Search

Navigation