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Structure Determination of an Unusual [2.2]paracyclophane Derivative by NMR Spectroscopy

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Abstract

Our ongoing study on cycloaddition reactions of dienes with different dienophiles afforded a great variety of derivatives with interesting molecular structures and electronic behavior. A new type of angularly annelated [2.2]paracyclophane (3) has been synthesize by the Diels–Alder reaction of 4-(2-propenyl[2.2]paracyclophane (1) and 1,4-benzoquinone (2) under high pressure conditions. The structure determination of this compound has been achieved by NMR measurements and semiempirical calculations.

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References

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Authors and Affiliations

  1. Institute of Structural Chemistry, Chemical Research Center of the Hungarian Academy of Sciences, Budapest, Hungary, P.O. Box 17, H-1525

    Eszter Gács-Baitz & Orsolya Egyed

  2. Dipartimento di Chimica, Università degli Studi di Perugia, via Elce di Sotto 8, Perugia, Italy, 06123

    Aldo Taticchi, Lucio Minuti & Assunta Marrocchi

Authors
  1. Eszter Gács-Baitz
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  2. Orsolya Egyed
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  3. Aldo Taticchi
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  4. Lucio Minuti
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  5. Assunta Marrocchi
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Correspondence to Orsolya Egyed.

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Gács-Baitz, E., Egyed, O., Taticchi, A. et al. Structure Determination of an Unusual [2.2]paracyclophane Derivative by NMR Spectroscopy. Struct Chem 16, 581–585 (2005). https://doi.org/10.1007/s11224-005-6098-1

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  • DOI: https://doi.org/10.1007/s11224-005-6098-1

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