Skip to main content
SpringerLink
Log in

Reaction of 1,1,3,3-tetramethyldisiloxane with p-substituted acetophenones in the presence of platinum and rhodium complexes

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Hydrosilylation of p-substituted acetophenones XC6H4COCH3 (X = H, Me, MeO, HO, F, Cl, NO2) with 1,1,3,3-tetramethyldisiloxane in the presence of rhodium and platinum complexes was studied. The Pt(II) complexes are less active but more selective catalysts of hydrosilylation of acetophenones. Six new 1-(1′-arylethoxy)-1,1,3,3-tetramethyldisiloxanes were prepared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Comprehensive Handbook on Hydrosilylation, Marcinec, B., Ed., Oxford: Pergamon, 1992.

    Google Scholar 

  2. Brunner, H., J. Organomet. Chem., 1986, vol. 300, nos.1–2, p. 39.

    Google Scholar 

  3. Reznikov, A.N., Lobadyuk, V.I., Spevak, V.N., and Skvortsov, N.K., Zh. Obshch. Khim., 1998, vol. 68, no.6, p. 960.

    Google Scholar 

  4. Lasitsa, N.A., Skvortsov, N.K., Lobadyuk, V.I., Spevak, V.N., Esina, G.A., Abramova, I.P., and Lazarev, S.Ya., Zh. Obshch. Khim., 1992, vol. 62, no.8, p. 1864.

    Google Scholar 

  5. Vekki, D.A. de, Ol’sheev, V.A., Spevak, V.N., and Skvortsov, N.K., Zh. Obshch. Khim., 2001, vol. 71, no.12, p. 2017.

    Google Scholar 

  6. Vekki, D.A. de and Skvortsov, N.K., Zh. Obshch. Khim., 2004, vol. 74, no.2, p. 224.

    Google Scholar 

  7. Brunner, H. and Rahman, A.F.M.M., Chem. Ber., 1984, vol. 117, no.2, p. 710.

    Google Scholar 

  8. Vekki, D.A. de, Viktorovskii, I.V., and Skvortsov, N.K., Zh. Obshch. Khim., 2004, vol. 74, no.9, p. 1426.

    Google Scholar 

  9. Brunner, H., Reiter, B., and Riepl, G., Chem. Ber., 1984, vol. 117, no.4, p. 1330.

    Google Scholar 

  10. Spevak, V.N., Vekki, D.A. de, Bel’skii, V.K., Stash, A.I., and Skvortsov, N.K., Abstracts of Papers, XXI Mezhdunarodnaya Chugaevskaya konferentsiya po koordinatsionnoi khimii (XXI Int. Chugaev Conf. on Coordination Chemistry), Kiev, 2003, p. 128.

  11. Skvortsov, N.K., Zh. Obshch. Khim., 1993, vol. 63, no.5, p. 961.

    Google Scholar 

  12. Lobadyuk, V.I., Spevak, V.N., and Skvortsov, N.K., Zh. Obshch. Khim., 1996, vol. 66, no.5, p. 871.

    Google Scholar 

  13. Ojima, I., Yamamoto, K., and Kumada, M., Aspects of Homogeneous Catalysis, Ugo, R., Ed., Dordrecht: Reidel, 1977, vol. 3, p. 185.

    Google Scholar 

  14. Reikhsfeld, V.O., Astrakhanov, M.I., and Kagan, E.G., Zh. Obshch. Khim., 1970, vol. 40, no.3, p. 699.

    Google Scholar 

  15. Joy, J.R. and Orchin, M., J. Am. Chem. Soc., 1959, vol. 81, no.2, p. 305.

    Google Scholar 

  16. Spevak, V.N., Skvortsov, N.K., Bel’skii, V.K., Konovalov, V.E., and Lobadyuk, V.I., Zh. Obshch. Khim., 1992, vol. 62, no.12, p. 2646.

    Google Scholar 

  17. Vekki, D.A. de, Spevak, V.N., and Skvortsov, N.K., Koord. Khim., 2001, vol. 27, no.8, p. 617.

    Google Scholar 

  18. Bokach, N.A., Selivanov, S.I., Kukushkin, V.Y., Haukka, M., Silva, M.F.C. da G., and Pombeiro, A.J.L., Eur. J. Inorg. Chem., 2001, no. 11, p. 2805.

  19. Varshavskii, Yu.S., Cherkasova, T.G., Zh. Neorg. Khim., 1967, vol. 12, no.6, p. 1709.

    Google Scholar 

  20. Brauer, G., Handbuch der praparativen anorganischen Chemie, Stuttgart: Ferdinand Enke, 1954. Translated under the title Rukovodstvo po neorganicheskomu sintezu, Moscow: Mir, 1986, vol. 6, p. 1867.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    V. V. Zuev, D. A. de Vekki, A. E. Kuchaev, M. V. Vorob’ev & N. K. Skvortsov

  2. St. Petersburg State Institute of Technology, St. Petersburg, Russia

    V. V. Zuev, D. A. de Vekki, A. E. Kuchaev, M. V. Vorob’ev & N. K. Skvortsov

Authors
  1. V. V. Zuev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. de Vekki
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. E. Kuchaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. V. Vorob’ev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. K. Skvortsov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 11, 2004, pp. 1804–1811.

Original Russian Text Copyright © 2004 by Zuev, de Vekki, Kuchaev, Vorob’ev, Skvortsov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zuev, V.V., de Vekki, D.A., Kuchaev, A.E. et al. Reaction of 1,1,3,3-tetramethyldisiloxane with p-substituted acetophenones in the presence of platinum and rhodium complexes. Russ J Gen Chem 74, 1679–1685 (2004). https://doi.org/10.1007/s11176-005-0083-7

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11176-005-0083-7

Keywords

Search

Navigation