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Hydrosilylation of Allyl Ethers in the Presence of Supported Sulfur-Containing Platinum(II) Complexes

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Abstract

Hydrosilylation of allyl ethyl, allyl butyl, allyl glycidyl, allyl benzyl, and allyl phenyl ethers by 1,1,3,3-tetramethyldisiloxane in the presence of supported sulfur-containing platinum(II) complexes with the general formula [{SiO2}O2Si(Me)(CH2)3SR]2PtCl2 (R = Bu, Hex, Bn; {SiO2} is silica surface) and side processes have been studied.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Moskovskii pr. 26, St. Petersburg, 190013, Russia

    D. A. de Vekki, M. A. Il’ina & N. K. Skvortsov

Authors
  1. D. A. de Vekki
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  2. M. A. Il’ina
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  3. N. K. Skvortsov
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Correspondence to M. A. Il’ina.

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Original Russian Text © D.A. de Vekki, M.A. Il’ina, N.K. Skvortsov, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 1, pp. 28–38.

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de Vekki, D.A., Il’ina, M.A. & Skvortsov, N.K. Hydrosilylation of Allyl Ethers in the Presence of Supported Sulfur-Containing Platinum(II) Complexes. Russ J Gen Chem 88, 25–35 (2018). https://doi.org/10.1134/S107036321801005X

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