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Fluorescent sensor for Zn2+ cations based on a 4-methoxy-1,8-naphthalimide derivative containing a dipicolylamine receptor fragment

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Abstract

A previously undescribed fluorescent sensor for zinc cations based on a 4-methoxynaphthalimide fluorophore and a receptor fragment represented by a dipicolylamine derivative was synthesized, and its spectral and luminescent properties were studied. The resulting fluorescent sensor demonstrated fluorescence enhancement upon complexation with Zn2+ cations due to the formation of ligand—metal complexes with a composition of 1: 1, in which the electron transfer process is suppressed.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119334, Moscow, Russian Federation

    M. A. Pavlova, P. A. Panchenko & O. A. Fedorova

  2. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    P. A. Panchenko, M. N. Vlasova & O. A. Fedorova

Authors
  1. M. A. Pavlova
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  2. P. A. Panchenko
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  3. M. N. Vlasova
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  4. O. A. Fedorova
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Corresponding author

Correspondence to M. A. Pavlova.

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The authors declare no competing interests.

Additional information

The study of the complexation of sensor 5 with metal cations by optical and NMR spectroscopy was carried out with the support of the Ministry of Science and Higher Education of the Russian Federation using the scientific equipment of the Center for Research of the Structure of Molecules, A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.

This work was financially supported by the Russian Science Foundation (Project No. 20-73-10186).

No human or animal subjects were used in this research.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 9, pp. 2154–2161, September, 2023.

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Pavlova, M.A., Panchenko, P.A., Vlasova, M.N. et al. Fluorescent sensor for Zn2+ cations based on a 4-methoxy-1,8-naphthalimide derivative containing a dipicolylamine receptor fragment. Russ Chem Bull 72, 2154–2161 (2023). https://doi.org/10.1007/s11172-023-4011-y

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  • DOI: https://doi.org/10.1007/s11172-023-4011-y

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