Abstract
Electrolytes providing a high capacity (up to 400 mA h g−1) of an organic anode material, which is based on a polymeric product of a condensation of triquinoyl with an aromatic amine, in a lithium half-cell have been developed and studied. A complex study of a 1 M solution of LiPF6 in tetraglyme, which belongs to the gelled electrolytes, has been carried out. It is shown that practically no solid electrolyte interphase is formed at the interfaces with lithium and organic electrodes, which makes it possible to monitor the reaction occurring on the electrodes.
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C. Friebe, A. Lex-Balducci, U.S. Schubert, ChemSusChem, 2019, 12, 4093; DOI: https://doi.org/10.1002/cssc.201901545.
Y. Lu, J. Chen, Nat. Rev. Chem., 2020, 4, 127; DOI: https://doi.org/10.1038/s41570-020-0160-9.
H. Oubaha, J.-F. Gohy, S. Melinte, ChemPlusChem, 2019, 84, 1179; DOI: https://doi.org/10.1002/cplu.201800652.
A. A. Ignatova, O. V. Yarmolenko, Alternativnaya energetica i ecologiya [Alternative energy and ecology], 2015, 08–09, 112 (in Russian); DOI: https://doi.org/10.15518/isjaee.2015.08-09.014.
S. G. Kostryukov, O. Yu. Chernyaeva, B. S. Tanaseichuk, A. Sh. Kozlov, M. K. Pryanichnikova, A. A. Burtasov, Russ. Chem. Bull., 2020, 69, 1321; DOI: https://doi.org/10.1007/s11172-020-2905-5.
E. A. Komissarova, V. E. Zhulanov, I. G. Mokrushin, A. N. Vasyanin, E. V. Shklyaeva, G. G. Abashev, Russ. Chem. Bull., 2020, 69, 1944; DOI: https://doi.org/10.1007/s11172-020-2983-4.
J. J. Shea, C. Luo, ACS Appl. Mater. Interfaces, 2020, 12, 5361; DOI: https://doi.org/10.1021/acsami.9b20384.
G. R. Baymuratova, K. G. Khatmullina, I. K. Yakuschenko, G. Z. Tulibaeva, T. A. Savinykh, P. A. Troshin, A. F. Shestakov, O. V. Yarmolenko, J. Electroanal. Chem., 2021, 889, 115234; DOI: https://doi.org/10.1016/j.jelechem.2021.115234.
L. Aguilera, Sh. Xiong, J. Scheers, A. Matic, J. Mol. Liquids, 2015, 210, 238; DOI: https://doi.org/10.1016/j.molliq.2015.04.053.
S. Tobishima, H. Morimoto, M. Aoki, Y. Saito, T. Inose, T. Fukumoto, T. Kuryu, Electrochim. Acta, 2004, 49, 979; DOI: https://doi.org/10.1016/j.electacta.2003.10.009.
W. A. Henderson, J. Phys. Chem. B, 2006, 110, 13177; DOI: https://doi.org/10.1021/jp061516t.
W. A. Henderson, N. R. Brooks, V. G. Young, Jr., Chem. Mater, 2003, 15, 4685; DOI: https://doi.org/10.1021/cm034352r.
J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865; DOI: https://doi.org/10.1103/PhysRevLett.77.3865.
D. N. Laikov, Chem. Phys. Lett., 1997, 281, 151; DOI: https://doi.org/10.1016/S0009-2614(97)01206-2.
Y. Sun, I. Hamada, J. Phys. Chem. B, 2018, 122, 10014; DOI: https://doi.org/10.1021/acs.jpcb.8b07098.
M. Callsen, K. Sodeyama, Z. Futera, Y. Tateyama, I. Hamada, J. Phys. Chem. B, 2017, 121, 180; DOI: https://doi.org/10.1021/acs.jpcb.6b09203.
S. Tsuzuki, W. Shinoda, M. Matsugami, Y. Umebayashi, K. Ueno, T. Mandai, S. Seki, K. Dokko, M. Watanabe, Phys. Chem. Chem. Phys., 2015, 17, 126; DOI: https://doi.org/10.1039/C4CP04718D.
G. Z. Tulibaeva, O. V. Yarmolenko, A. F. Shestakov, Russ. Chem. Bull., 2009, 58, 1589; DOI: https://doi.org/10.1007/s11172-009-0218-9.
A. A. Ignatova, O. V. Yarmolenko, G. Z. Tulibaeva, A. F. Shestakov, S. A. Fateev, J. Power Sources, 2016, 309, 116; DOI: https://doi.org/10.1016/j.jpowsour.2016.01.075.
A. A. Slesarenko, G. Z. Tulibaeva, G. R. Baymuratova, A. V. Yudina, A. F. Shestakov, O. V. Yarmolenko, Russ. J. Electrochem., 2021, 57, 733; DOI: https://doi.org/10.1134/S1023193521070119.
D. Morales, R. E. Ruther, J. Nanda, S. Greenbaum, Electrochim. Acta, 2019, 304, 239; DOI: https://doi.org/10.1016/j.electacta.2019.02.110.
M. Kartal, A. Alp, H. Akbulut, Acta Phys. Polonica A, 2016, 129, 816; DOI: https://doi.org/10.12693/APhysPolA.129.816.
C. Ó. Laoire, S. Mukerjee, E. J. Plichta, M. A. Hendrickson, K. M. Abraham, J. Electrochem. Soc., 2011, 158, A302; DOI: https://doi.org/10.1149/1.3531981.
V. Ramezankhani, I. K. Yakuschenko, S. Vasilyev, T. A. Savinykh, A. V. Mumyatov, I. S. Zhidkov, E. V. Shchurik, E. Z. Kurmaev, A. F. Shestakov, P. A. Troshin, J. Mater. Chem. A, 2022, 10, 3044; DOI: https://doi.org/10.1039/D1TA05815K.
G. R. Baymuratova, A. V. Mumyatov, R. R. Kapaev, P. A. Troshin, O. V. Yarmolenko, Russ. J. Electrochem., 2021, 57, 725; DOI: https://doi.org/10.1134/S102319352107003X.
A. F. Shestakov, O. E. Romanuyk, A. V. Mumyatov, S. Yu. Luchkin, A. A. Slesarenko, O. V. Yarmolenko, K. J. Stevenson, P. A. Troshin, J. Electroanalyt. Chem., 2019, 836, 143; DOI: https://doi.org/10.1016/j.jelechem.2019.01.063.
O. V. Yarmolenko, O. E. Romanyuk, A. A. Slesarenko, G. R. Baymuratova, N. I. Shuvalova, A. V. Mumyatov, P. A. Troshin, A. F. Shestakov, Russ. J. Electrochem., 2019, 55, 254; DOI: https://doi.org/10.1134/S1023193519020174.
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This work was performed within the framework of the state task (State registration No. AAAA-A19-119071190044-3).
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2108–2115, October, 2022.
No human or animal subjects were used in this research.
The authors declare no competing interests.
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Baymuratova, G.R., Khatmullina, K.G., Tulibaeva, G.Z. et al. Gelled tetraglyme-based electrolyte for organic electrode materials. Russ Chem Bull 71, 2108–2115 (2022). https://doi.org/10.1007/s11172-022-3634-8
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DOI: https://doi.org/10.1007/s11172-022-3634-8