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Kinetics and mechanism of gold anode corrosion in a weakly basic aqueous solution of triethylenetetramine

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Abstract

The electrochemical corrosion of a gold anode in a weakly basic aqueous solution of triethylenetetramine was studied. Scanning and transmission electron microscopy revealed the formation of a compact gold deposit on the cathode and gold nanoparticles in the electrolyte. The kinetics and mechanism of the corrosion of the gold anode were studied by gravimetry and cyclic voltammetry. The formation of colloidal gold particles in solution was established by transmission electron microscopy.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Laptev, M. D. Vedenyapina, V. V. Kuznetsov, S. A. Kulaishin, M. M. Kazakova & E. D. Streltsova

Authors
  1. A. A. Laptev
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  2. M. D. Vedenyapina
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  3. V. V. Kuznetsov
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  4. S. A. Kulaishin
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  5. M. M. Kazakova
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  6. E. D. Streltsova
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Corresponding author

Correspondence to M. D. Vedenyapina.

Additional information

The authors are grateful to the Department of Structural Studies of the N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences for electron microscopic examination of the samples.

No human or animal subjects were used in this research.

The authors declare no competing interests.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1158–1163, June, 2022.

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Laptev, A.A., Vedenyapina, M.D., Kuznetsov, V.V. et al. Kinetics and mechanism of gold anode corrosion in a weakly basic aqueous solution of triethylenetetramine. Russ Chem Bull 71, 1158–1163 (2022). https://doi.org/10.1007/s11172-022-3516-0

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  • DOI: https://doi.org/10.1007/s11172-022-3516-0

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