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Corrosion of Gold Anode in an Aqueous Solution of N,N-Dimethylpropane-1,3-diamine

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Abstract

The kinetics and mechanism of corrosion of gold anode in a weakly basic aqueous solution of N,N-dimethylpropane-1,3-diamine have been studied by cyclic voltammetry and gravimetry. According to the scanning and transmission electron microscopy data, the corrosion products of gold anode are reduced at both steel and platinum cathodes under galvanostatic conditions to give not only electrolytic gold deposit but also colloidal gold nanoparticles in the electrolyte.

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ACKNOWLEDGMENTS

The authors thank the Structural Studies Department of the Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, for performing electron microscopic studies.

Funding

This study was financially supported by the Program for Development of Scientific Schools of the Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences.

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Correspondence to M. D. Vedenyapina.

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Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 9, pp. 1267–1274 https://doi.org/10.31857/S0514749221090056.

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Vedenyapina, M.D., Kuznetsov, V.V., Kulaishin, S.A. et al. Corrosion of Gold Anode in an Aqueous Solution of N,N-Dimethylpropane-1,3-diamine. Russ J Org Chem 57, 1417–1422 (2021). https://doi.org/10.1134/S1070428021090050

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