Abstract
The kinetics and mechanism of corrosion of gold anode in a weakly basic aqueous solution of N,N-dimethylpropane-1,3-diamine have been studied by cyclic voltammetry and gravimetry. According to the scanning and transmission electron microscopy data, the corrosion products of gold anode are reduced at both steel and platinum cathodes under galvanostatic conditions to give not only electrolytic gold deposit but also colloidal gold nanoparticles in the electrolyte.
Similar content being viewed by others
REFERENCES
Zhang, X.M. and Senanayake, G., Miner. Process. Extr. Metall. Rev., 2016, vol. 37, p. 385. https://doi.org/10.1080/08827508.2016.1218872
Konyratbekova, S.S., Baikonurova, A., and Akcil, A., Miner. Process. Extr. Metall. Rev., 2015, vol. 36, p. 198. https://doi.org/10.1080/08827508.2014.942813
Simakova, A.P., Vedenyapina, M.D., Kuznetsov, V.V., Makhova, N.N., and Vedenyapin, A.A., Russ. J. Phys. Chem. A, 2014, vol. 88, p. 331. https://doi.org/10.1134/S0036024414020241
Vedenyapina, M.D., Kuznetsov, V.V., Makhova, N.N., and Vedenyapin, A.A., Russ. J. Phys. Chem. A, 2016, vol. 90, p. 1903. https://doi.org/10.1134/S0036024416090284
Vedenyapina, M.D., Kuznetsov, V.V., Rodikova, D.I., Makhova, N.N., and Vedenyapin, A.A., Mendeleev Commun., 2018, vol. 28, p. 181. https://doi.org/10.1016/j.mencom.2018.03.024
Vedenyapina, M.D., Kuznetsov, V.V., Makhova, N.N., and Rodikova, D.I., Russ. J. Phys. Chem. A, 2019, vol. 93, p. 466. https://doi.org/10.1134/S0036024419020304
Vedenyapina, M.D., Ubushieva, G.Ts., Kuznetsov, V.V., Makhova, N.N., and Vedenyapin, A.A., Russ. J. Phys. Chem. A, 2016, vol. 90, p. 2312. https://doi.org/10.1134/S0036024416110297
Vedenyapina, M.D., Kuznetsov, V.V., Makhova, N.N., and Rodikova, D.I., Russ. Chem. Bull., Int. Ed., 2020, vol. 69, p. 1884. https://doi.org/10.1007/s11172-020-2974-5
Vedenyapina, M.D., Kuznetsov, V.V., Dmitrenok, A.S., Minyaev, M.E., Makhova, N.N., and Kazakova, M.M., Russ. Chem. Bull., Int. Ed., 2021, vol. 70, p. 735. https://doi.org/10.1007/s11172-021-3144-0
Vedenyapina, M.D., Kuznetsov, V.V., Makhova, N.N., and Rodikova, D.I., Russ. Chem. Bull., Int. Ed., 2019, vol. 68, p. 1997. https://doi.org/10.1007/s11172-019-2658-1
Dykman, L.A. and Khlebtsov, N.G., Russ. Chem. Rev., 2019, vol. 88, p. 229. https://doi.org/10.1070/RCR4843
Saldan, I., Dobrovtseva, O., Sus, L., Makota, O., Pereviznyk, O., Kuntyi, O., and Reshetnyak, O., J. Solid State Electrochem., 2018, vol. 22, p. 637.
Laviron, E., J. Electroanal. Chem. Interfacial Electrochem., 1979, vol. 101, p. 19.
Kachala, V.V., Khemchyan, L.L., Kashin, A.S., Orlov, N.V., Grachev, A.A., Zalesskiy, S.S., and Ananikov, V.P., Russ. Chem. Rev., 2013, vol. 82, p. 648. https://doi.org/10.1070/RC2013v082n07ABEH004413
ACKNOWLEDGMENTS
The authors thank the Structural Studies Department of the Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, for performing electron microscopic studies.
Funding
This study was financially supported by the Program for Development of Scientific Schools of the Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare no conflict of interest.
Additional information
Translated from Zhurnal Organicheskoi Khimii, 2021, Vol. 57, No. 9, pp. 1267–1274 https://doi.org/10.31857/S0514749221090056.
Rights and permissions
About this article
Cite this article
Vedenyapina, M.D., Kuznetsov, V.V., Kulaishin, S.A. et al. Corrosion of Gold Anode in an Aqueous Solution of N,N-Dimethylpropane-1,3-diamine. Russ J Org Chem 57, 1417–1422 (2021). https://doi.org/10.1134/S1070428021090050
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070428021090050