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Catalytic effect of aliphatic amine on the reaction of quinone diimine with 2-mercaptobenzothiazole

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Abstract

A secondary aliphatic amine, N-benzylmethylamine, significantly increases the rate of the chain reaction of N,N′-diphenyl-1,4-benzoquinone diimine with 2-mercaptobenzothiazole in toluene. The kinetic study shows that the increase in the rate is observed at the step of radical generation (chain initiation). The catalytic effect is due to secondary reactions involving a salt of N-benzylmethylamine with 2-mercaptobenzothiazole, which is formed in the system.

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  1. Institute of Problems of Chemical Physics of the Russian Academy of Sciences, 1 prosp. Acad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. T. Varlamov

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Correspondence to V. T. Varlamov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 694–700, April, 2022.

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Varlamov, V.T. Catalytic effect of aliphatic amine on the reaction of quinone diimine with 2-mercaptobenzothiazole. Russ Chem Bull 71, 694–700 (2022). https://doi.org/10.1007/s11172-022-3467-5

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  • DOI: https://doi.org/10.1007/s11172-022-3467-5

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