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Mercury(II) chloride in the synthesis of nido-carborane derivatives with B-N, B-O, and B-S bonds

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Abstract

The use of mercury(II) chloride for the synthesis of nido-carborane derivatives with B-O, B-N, and B-S bonds was considered. The involvement of HgCl2 allows one to selectively obtain symmetrically substituted nido-carborane derivatives in high yields. The resulting derivatives can undergo various modification reactions of the organic substituent or be used in the synthesis of metallacarboranes. The structure of the 8,8′-di(dimethyl sulfide)-6,6′-diphenyl derivative of iron(II) bis(dicarbollide) was determined by single-crystal X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russia

    M. Yu. Stogniy, S. A. Anufriev, E. V. Bogdanova, I. B. Sivaev & V. I. Bregadze

  2. M. V. Lomonosov Moscow State University of Fine Chemical Technologies, RTU-MIREA, 86 prosp. Vernadskogo, 119571, Moscow, Russia

    M. Yu. Stogniy

  3. G. V. Plekhanov Russian University of Economics, 36 Stremyanny per., 117997, Moscow, Russia

    I. B. Sivaev

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  1. M. Yu. Stogniy
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  2. S. A. Anufriev
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  3. E. V. Bogdanova
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  4. I. B. Sivaev
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  5. V. I. Bregadze
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Correspondence to M. Yu. Stogniy.

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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 91–101, January, 2022.

This work was financially supported by the Russian Science Foundation (Project No. 19-73-00353). X-ray diffraction and NMR spectroscopic studies were carried out using scientific equipment of the Center for Molecular Structure Studies at the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences with financial support of the Ministry of Science and Higher Education of the Russian Federation.

The authors are grateful to K. Yu. Suponitskiy for performing X-ray diffraction studies.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Stogniy, M.Y., Anufriev, S.A., Bogdanova, E.V. et al. Mercury(II) chloride in the synthesis of nido-carborane derivatives with B-N, B-O, and B-S bonds. Russ Chem Bull 71, 91–101 (2022). https://doi.org/10.1007/s11172-022-3381-x

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