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Oxidation of dicarbadodecahydronidoundecaborate anions by mercuric chloride in tetrahydrofuran and pyridine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

It was found that mercuric chloride has a specific oxidative effect on the anions of dicarbadodecahydronidoundecaborates in THF or pyridine, which consists in the preferential replacement of hydride hydrogen by the ligand in the 8 position of the anion.

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Literature cited

  1. D. C. Young, D. V. Home, and H. F. Hawthorne, J. Am. Chem. Soc.,91, 859 (1969).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Zakharkin, V. N. Kalinin & G. G. Zhigareva

Authors
  1. L. I. Zakharkin
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  2. V. N. Kalinin
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  3. G. G. Zhigareva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2376–2377, October, 1979.

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Zakharkin, L.I., Kalinin, V.N. & Zhigareva, G.G. Oxidation of dicarbadodecahydronidoundecaborate anions by mercuric chloride in tetrahydrofuran and pyridine. Russ Chem Bull 28, 2198–2199 (1979). https://doi.org/10.1007/BF00947583

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  • DOI: https://doi.org/10.1007/BF00947583

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