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Synthesis of podands with nido-carboranyl groups as a basis for construction of crown ethers with an incorporated metallacarborane moiety

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Abstract

The reactions of the dioxane derivative of 7,8-dicarba-nido-undecaborate anion (nido-carborane), [10-O(CH2CH2)2O-nido-7,8-C2B9H11], with a series of O,O′-dinucleophiles (pyrocatechol, resorcinol, hydroquinone, and ethylene glycol) were studied. The nido-carborane-based podand was obtained, which can be used for assembling of crown ethers with an inserted metallacarborane moiety.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    M. Yu. Stogniy, G. S. Kazakov, I. B. Sivaev & V. I. Bregadze

  2. M. V. Lomonosov Moscow State University of Fine Chemical Technologies, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    G. S. Kazakov

Authors
  1. M. Yu. Stogniy
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  2. G. S. Kazakov
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  3. I. B. Sivaev
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  4. V. I. Bregadze
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Correspondence to M. Yu. Stogniy.

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Dedicated to the Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0699–0704, March, 2013.

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Stogniy, M.Y., Kazakov, G.S., Sivaev, I.B. et al. Synthesis of podands with nido-carboranyl groups as a basis for construction of crown ethers with an incorporated metallacarborane moiety. Russ Chem Bull 62, 699–704 (2013). https://doi.org/10.1007/s11172-013-0095-0

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  • DOI: https://doi.org/10.1007/s11172-013-0095-0

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