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Palladium carbonyl complexes with anions of N-heterocyclic carboxylic and pyridine-2-sulfonic acids

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Abstract

Synthesis, spectral characteristics, and structure of palladium(I) carbonyl complexes containing anions of N-heterocyclic carboxylic acids and pyridine-2-sulfonic acid of the general formula [Pd(CO)(NHC-CO2)]n/[Pd(CO)(NHC-SO3)]n, where NHC is an N-heterocycle, were described. The resulting complexes can be attributed to a binuclear structure with bridging or terminal coordination of carbonyl ligands depending on the nature of the substituents in the heterocycle.

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Authors and Affiliations

  1. M. V. Lomonosov Institute of Fine Chemical Technologies, MIREA — Russian Technological University, 86 prosp. Vernadskogo, 117561, Moscow, Russian Federation

    O. N. Shishilov & V. R. Flid

  2. A. A. Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, 49 Leninsky prosp., 119991, Moscow, Russian Federation

    N. S. Akhmadullina

Authors
  1. O. N. Shishilov
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  2. N. S. Akhmadullina
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  3. V. R. Flid
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Correspondence to O. N. Shishilov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0289–0294, February, 2020.

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Shishilov, O.N., Akhmadullina, N.S. & Flid, V.R. Palladium carbonyl complexes with anions of N-heterocyclic carboxylic and pyridine-2-sulfonic acids. Russ Chem Bull 69, 289–294 (2020). https://doi.org/10.1007/s11172-020-2758-y

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  • DOI: https://doi.org/10.1007/s11172-020-2758-y

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