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Kinetic model for cyclohexene hydromethoxycarbonylation catalyzed by RuCl3

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Abstract

A kinetic model for hydromethoxycarbonylation of cyclohexene in methanol in the presence of RuCl3 at 463 K was developed. The model shows a combined influence of different reactants on the reaction rate; it takes into account side reactions of cyclohexene and it satisfactorily describes the experimental data obtained at conversions of cyclohexene up to 75%.

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Authors and Affiliations

  1. Tula State Lev Tolstoy Pedagogical University, 125 Lenin prosp., 300026, Tula, Russian Federation

    N. T. Sevostyanova & S. A. Batashev

Authors
  1. N. T. Sevostyanova
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  2. S. A. Batashev
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Correspondence to N. T. Sevostyanova.

Additional information

Based on the materials of the V All-Russian Organic Chemistry Conference (ROCC-V) (September 10–14, 2018, Vladikavkaz, Russia).

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Sevostyanova, N.T., Batashev, S.A. Kinetic model for cyclohexene hydromethoxycarbonylation catalyzed by RuCl3. Russ Chem Bull 68, 540–546 (2019). https://doi.org/10.1007/s11172-019-2451-1

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  • DOI: https://doi.org/10.1007/s11172-019-2451-1

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