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Carbonylation of 1-nonene on Pd(II) complexes in alcohols at low CO pressure

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The yields of the products of the carbonylation of 1-nonene in normal alcohols upon catalysis by palladium (II) complexes and low carbon monoxide pressures increases with increasing molecular mass of the alcohol, while the selectivity remains virtually the same.

  2. 2.

    The dilution of the alcohol by acetone does not affect the yields of the carbonylation of 1-nonene in 1-propanol but causes a decrease in this yield in 1-butanol and 1-heptanol. The selectivity decreases upon the addition of acetone to all the alcohols studied.

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Authors and Affiliations

  1. L. Ya. Karpov Physical Chemistry Institute, Moscow

    A. D. Karpyuk, M. I. Terekhova, N. D. Kolosova, É. S. Petrov & I. P. Beletskaya

Authors
  1. A. D. Karpyuk
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  2. M. I. Terekhova
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  3. N. D. Kolosova
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  4. É. S. Petrov
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  5. I. P. Beletskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 233–235, January, 1985.

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Karpyuk, A.D., Terekhova, M.I., Kolosova, N.D. et al. Carbonylation of 1-nonene on Pd(II) complexes in alcohols at low CO pressure. Russ Chem Bull 34, 221–222 (1985). https://doi.org/10.1007/BF01157368

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  • DOI: https://doi.org/10.1007/BF01157368

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