Skip to main content
Log in

Influence of aging of poly[(trimethylsilyl)prop-1-yne] on the thermodynamics of sorption of light hydrocarbons

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Changes in the properties of the poly[(trimethylsilyl)prop-1-yne] (PTMSP) film deposited on the walls of a quartz capillary under the action of high temperatures were studied by chromatographic methods. The change in the thermodynamic parameters of sorption of light hydrocarbons related to both physical aging of the PTMSP film and, possibly, its chemical destruction was examined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. W. Baker, Ind. Eng. Chem. Res., 2002, 41, 1393.

    Article  CAS  Google Scholar 

  2. B. D. Freeman, I. Pinnau, in Polymer Membranes for Gas and Vapor Separation: Chemistry and Materials Science, Eds B. D. Freeman, I. Pinnau, 1999.

  3. K. Ghosal, B. D. Freeman, Polymers for Advanced Technologies, 1994, 5,673.

    Article  CAS  Google Scholar 

  4. J. Schultz, K. V. Peinemann, J. Membr. Sci., 1996, 110,37.

    Article  CAS  Google Scholar 

  5. S. D. Kelman, PhD Thesis, The University of Texas at Austin, 2008.

  6. T. C. Merkel, R. P. Gupta, B. S. Turk, B. D. Freeman, J. Memb. Sci., 2001, 191,85.

    Article  CAS  Google Scholar 

  7. T. C. Merkel, Z. He, I. Pinnau, B. D. Freeman, P. Meakin, A. J. Hill, Macromolecules, 2003, 36, 6844.

    Article  CAS  Google Scholar 

  8. Yu. Yampolskii, L. Starannikova, N. Belov, M. Bermeshev, M. Gringolts, E. Finkelshtein, J. Membr. Sci., 2014, 453,532.

    Article  CAS  Google Scholar 

  9. I. Pinnau, L. G. Toy, J. Membr. Sci., 1996, 116,199.

    Article  CAS  Google Scholar 

  10. T. S. Chow, Macromolecules, 1984, 17, 2336.

    Article  CAS  Google Scholar 

  11. N. Morlière, C. Vallières, L. Perrin, D. Roizard, J. Membr. Sci., 2006, 270,123.

    Article  CAS  Google Scholar 

  12. T. Nakagawa, S. Fujisaki, H. Nakano, A. Higuchi, J. Membr. Sci., 1994, 94,183.

    Article  CAS  Google Scholar 

  13. V. Belotserkovskaya, E. Yakovleva, J. Chromatogr. A, 2013, 1298,109.

    Article  CAS  PubMed  Google Scholar 

  14. A. Morisato, H. C. Shen, S. S. Sankar, B. D. Freeman, I. Pinnau, C. G. Cassilas, J. Polym. Sci. Polym. Phys., 1996, 34, 2209.

    Article  CAS  Google Scholar 

  15. K. Nagai, S. Kanehashi, S. Tabei, T. Nakagaw, J. Membr. Sci., 2005, 251,101.

    Article  CAS  Google Scholar 

  16. A. Morisato, B. D. Freeman, I. Pinnau, C. G. Cassilas, J. Polym. Sci. Polym. Phys., 1996, 34, 1925.

    Article  CAS  Google Scholar 

  17. G. L. Baker, C. F. Klausner, A. S. Gozdz, J. A. Shelburne, T. N. Bowmer, Lithography and Photochemistry, Advances in Chemistry Series, 1990, 224,663.

    Google Scholar 

  18. K. Nagai, A. Higuchi, T. Nakagawa, J. Appl. Polym. Sci., 1994, 54, 1207.

    Article  CAS  Google Scholar 

  19. K. Nagai, A. Higuchi, T. Nakagawa, J. Appl. Polym. Sci., 1994, 54, 1353.

    Article  CAS  Google Scholar 

  20. S. Matteucci, V. A. Kusuma, D. Sanders, S. Swinnea, B. D. Freeman, J. Membr. Sci., 2008, 307,196.

    Article  CAS  Google Scholar 

  21. J. Jia, G. L. Baker, J. Polym. Sci., Part B: Polym. Phys., 1998, 36,959.

    Article  CAS  Google Scholar 

  22. S. D. Kelman, B. W. Rowe, C. W. Bielawski, S. J. Pas, A. J. Hill, D. R. Paul, B. D. Freeman, J. Membr. Sci., 2008, 320,123.

    Article  CAS  Google Scholar 

  23. I. Halasz, C. Horvath, Anal. Chem., 1963, 35,499.

    Article  CAS  Google Scholar 

  24. V. Golovnya, E. A. Mistryukov, J. High Resol. Chromatogr., 1979, 2,609.

    Article  CAS  Google Scholar 

  25. L. S. Ettre, J. V. Hinshaw, Basic Relationships of Gas Chromatography, Advanstar, Cleveland, 1993.

    Google Scholar 

  26. Y. V. Patrushev, E. Y. Yakovleva, I. K. Shundrina, D. P. Ivanov, T. S. Glazneva, J. Chromatogr., 2015, 1406,291.

    Article  CAS  Google Scholar 

  27. V. Yu. Belotserkovskaya, Doct. Sci. (Chem.) Thesis, G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 2011 (in Russian).

    Google Scholar 

  28. T. Masuda, B. Z. Tang, T. Higashimura, H. Yamaoka, Macromolecules, 1985, 18, 2369.

    Article  CAS  Google Scholar 

  29. V. E. Shiryaeva, T. P. Popova, A. A. Korolev, A. Yu. Kanat´eva, A. A. Kurganov, Zh. Fiz. Khim., 2018, in press [Russ. J. Phys. Chem. (Engl. Transl.), 2018].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. A. Kurganov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1307–1311, July, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shiryaeva, V.E., Korolev, A.A., Popova, T.P. et al. Influence of aging of poly[(trimethylsilyl)prop-1-yne] on the thermodynamics of sorption of light hydrocarbons. Russ Chem Bull 67, 1307–1311 (2018). https://doi.org/10.1007/s11172-018-2216-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-018-2216-2

Key words

Navigation