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Unusual Structural Changes of PIM-1 Polymer Detected by Means of Chromatographic Technique

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Abstract

Changes in retention factor k of light hydrocarbons on PIM-1 stationary phase with an increase of ageing temperature are tested. Varying the ageing temperature from 50 to 200°C causes a slight decrease in solute retention, which, however, changes to strong increase as soon as the ageing temperature exceeds 200°C. An increase of the solute retention factor k means the proportional increase of the Henry equilibrium constant K, which in turn under constant chromatographic conditions probably points out the thermodynamic changes in the structure of PIM-1 which can be caused either by a chemical decomposition or by a structural rearrangement. Due to high chemical stability of PIM-1, an increase of solute retention with thermal ageing is a consequence of structural rearrangements of polymeric chains, resulting in more adapted adsorption sites. At the same time, accessibility of the adsorption sites decreases as it is indicated by the reduction of column efficiency and diffusion coefficients.

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REFERENCES

  1. P. M. Budd, B. S. Ghanem, S. Makhseed, N. B. McKeown, K. J. Msayib, and C. E. Tattershall, Chem. Commun. 2004, 230 (2004).

    Article  Google Scholar 

  2. P. M. Budd, E. S. Elabas, B. S. Ghanem, S. Makhseed, N. B. McKeown, K. J. Msayib, C. E. Tattershall, and D. Wang, Adv. Mater. 16, 456 (2004).

    Article  CAS  Google Scholar 

  3. P. M. Budd, S. M. Makhseed, B. S. Ghanem, K. J. Msayib, C. E. Tattershall, and N. B. McKeown, Mater. Today 7, 40 (2004).

    Article  CAS  Google Scholar 

  4. N. B. McKeown, P. M. Budd, K. J. Msayib, B. S. Ghanem, H. Kingston, C. E. Tattershall, S. Makhseed, K. J. Reynolds, and D. Fritsch, Chem.- Eur. J. 11, 2610 (2005).

    Article  CAS  Google Scholar 

  5. D. Fritsch, N. B. McKeown, P. M. Budd, and K. J. Msayib, in Proceedings of the Advanced Membrane Technology II Conference, Kloster Irsee, Irsee, Germany, 2004 (Irsee, 2004).

  6. P. M. Budd, K. J. Msayib, C. E. Tattershall, B. S. Ghanema, K. J. Reynolds, N. B. McKeown, and D. Fritsch. J. Membr. Sci. 251, 263 (2005).

    Article  CAS  Google Scholar 

  7. J. Weber, N. Du, and M. D. Guiver, Macromolecules 44, 1763 (2011).

    Article  CAS  Google Scholar 

  8. A. Vishnyakov, P. I. Ravikovitch, and A. V. Neimark, Langmuir 15, 8736 (1999).

    Article  CAS  Google Scholar 

  9. J. Jagiello and M. Thommes, Carbon 42, 1227 (2004).

    Article  CAS  Google Scholar 

  10. D. Lozano-Castello, D. Cazorla-Amoros, and A. Linares-Solano, Carbon 42, 1233 (2004).

    Article  CAS  Google Scholar 

  11. P. Bernardo, F. Bazzarelli, F. Tasselli, G. Clarizia, C. R. Mason, L. Maynard-Atem, P. M. Budd, M. Lanc, K. Pilnacek, O. Vopicka, K. Friess, D. Fritsch, Yu. P. Yampolskii, V. Shantarovich, and J. C. Jansen, Polymer 113, 283 (2017).

    Article  CAS  Google Scholar 

  12. V. Shiryaeva, T. Popova, A. Korolev, A. Kanateva, and A. Kurganov, J. Sep. Sci. 41, 3404(2018).

    Article  CAS  Google Scholar 

  13. N. Morliere, C. Vallieres, L. Perrin, and D. Roizard, J. Membr. Sci. 270, 123 (2006).

    Article  CAS  Google Scholar 

  14. Yu. Yampolskii, L. Starannikova, N. Belov, M. Bermeshev, M. Gringolts, and E. Finkelshtein, J. Membr. Sci. 453, 532 (2014).

    Article  CAS  Google Scholar 

  15. E. Yakubenko, A. Korolev, P. Chapala, M. Bermeshev, A. Kanateva, and A. Kurganov, Anal. Chim. Acta 986, 153 (2017).

    Article  CAS  Google Scholar 

  16. L. S. Ettre and J. V. Hinshaw, Basic Relationships of Gas Chromatography (Advanstar, Cleveland, 1993).

    Google Scholar 

  17. J. R. Conder and C. L. Young, Physicochemical Measurements by Gas Chromatography (Wiley, Chichester, 1979).

    Google Scholar 

  18. A. A. Korolev, V. E. Shiryaeva, T. P. Popova, M. V. Bermeshev, A. Yu. Kanateva, and A. A. Kurganov, J. Chromatogr. A 1533, 174 (2018).

    Article  CAS  Google Scholar 

  19. A. Korolev, V. Shyrjaeva, T. Popova, and A. Kurganov, J. Chromatogr. A 1218, 3267 (2011).

    Article  CAS  Google Scholar 

  20. M. B. S. Lakshmi, B. Francis, and A. Kumar, in Transport Properties of Polymeric Membranes, Ed. by S. Thomas, R. Wilson, A. Kumar, and S. C. George (Elsevier, New York, 2018), Chap. 17, p. 349.

    Google Scholar 

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ACKNOWLEDGMENTS

This work was carried out within the State Program of A.V. Topchiev Institute of Petrochemical Synthesis of Russian Academy of Sciences (TIPS RAS).

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Authors and Affiliations

  1. A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 109548, Moscow, Russia

    V. E. Shiryaeva, T. P. Popova, A. Yu. Kanateva, A. A. Korolev & A. A. Kurganov

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  1. V. E. Shiryaeva
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  2. T. P. Popova
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  3. A. Yu. Kanateva
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  4. A. A. Korolev
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  5. A. A. Kurganov
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Correspondence to A. Yu. Kanateva or A. A. Kurganov.

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Shiryaeva, V.E., Popova, T.P., Kanateva, A.Y. et al. Unusual Structural Changes of PIM-1 Polymer Detected by Means of Chromatographic Technique. Polym. Sci. Ser. C 61, 198–204 (2019). https://doi.org/10.1134/S1811238219010168

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  • DOI: https://doi.org/10.1134/S1811238219010168

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