Skip to main content
SpringerLink
Log in

Synthesis, structures and utility of organogallium and organoindium complexes with oxo and thio ligands

  • Reviews
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The review is focused on synthesis and study of a variety of organogallium and organoindium complexes with several internally functionalized anionic oxo ligands, anionic dithio and organoseleno ligands. These compounds have been thoroughly characterized by elemental analyses, 1H, 13C, and 77Se NMR spectroscopy, and in several cases by single crystal X-ray diffraction analyses. Structural preferences in these complexes are influenced by the nature of the metal atom (Ga or In), organic group attached to it, and the incoming ligand with indium preferring to acquire higher coordination number. The complexes with oxo ligands show photo-luminescence with the emission quantum yields higher in general than the corresponding free ligands. The complexes with chalcogen ligands are versatile precursors for the synthesis of metal sulfide and selenide nanocrystals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. J. Downs, Chemistry of Aluminum, Gallium, Indium and Thallium, Blackie Acad. Profess., London, 1993, 526 pp.

    Book  Google Scholar 

  2. S. Schulz, in Comprehensive Organometallic Chemistry III, Eds R. H. Crabtree, D. M. P. Mingos, Elsevier, Oxford, 2007, Vol. 3, p. 287.

  3. S. Araki, T. Hirashita, in Comprehensive Organomettaic Chemistry III, Eds R. H. Crabtree, D. M. P. Mingos, Elsevier, Oxford, 2007, Vol. 9, p. 649.

  4. F. Hild, N. Neehaul, F. Bier, M. Wirsum, C. Gourlaouen, S. Dagorne, Organometallics, 2013, 32, 587.

    Article  CAS  Google Scholar 

  5. C. H. Chen, J. Shi, Coord. Chem. Rev., 1998, 171, 161.

    Article  CAS  Google Scholar 

  6. C. J. Carmalt, S. J. King, Coord. Chem. Rev., 2006, 250, 682.

    Article  CAS  Google Scholar 

  7. L. G. Bloor, C. J. Carmalt, D. Pugh, Coord. Chem. Rev., 2011, 255, 1293.

    Article  CAS  Google Scholar 

  8. S. Ghoshal, V. K. Jain, J. Chem. Sci., 2007, 119, 583.

    Article  CAS  Google Scholar 

  9. J. P. Phillips, Chem. Rev., 1956, 56, 271.

    Article  CAS  Google Scholar 

  10. C. W. Tang, S. A. van Slyke, Appl. Phys. Lett., 1987, 51, 913.

    Article  CAS  Google Scholar 

  11. H. Bi, D. Chen, D. Li, Y. Yuan, D. Xia, Z. Zhang, H. Zhang, Y. Wang, Chem. Commun., 2011, 47, 4135.

    Article  CAS  Google Scholar 

  12. M. L. Ramos, A. R. E. de Sousa, L. L. G. Justino, S. M. Fonseca, C. F. G. C. Geraldes, H. D. Burrows, Dalton Trans., 2013, 42, 3682.

    Article  CAS  Google Scholar 

  13. P. E. Burrows, L. S. Sapochak, D. M. McCarty, S. R. Forrest, M. E. Thompson, Appl. Phys. Lett., 1994, 64, 2718.

    Article  CAS  Google Scholar 

  14. M. Brinkmann, B. Fite, S. Pratontep, C. Chaumont, Chem. Mater., 2004, 16, 4627.

    Article  CAS  Google Scholar 

  15. A. R. Barron, Adv. Mater. Opt. Electron., 1995, 5, 245.

    Article  CAS  Google Scholar 

  16. D. P. Dutta, G. Sharma, S. Ghoshal, N. P. Kushwah, V. K. Jain, J. Nanosci. Nanotechnol., 2006, 6, 235.

    Article  CAS  Google Scholar 

  17. M. A. Malik, M. Afzaal, P. O’Brien, Chem. Rev., 2010, 110, 4417.

    Article  CAS  Google Scholar 

  18. J. E. Kwon, S. Y. Park, Adv. Mater., 2011, 23, 3615.

    Article  CAS  Google Scholar 

  19. J. Jhao, S. Ji, Y. Chen, H. Guo, P. Yang, Phys. Chem. Chem. Phys., 2012, 14, 8803.

    Article  Google Scholar 

  20. M. K. Pal, N. P. Kushwah, A. P. Wadawale, V. S. Sagoria, V. K. Jain, E. R. T. Tiekink, J. Organomet. Chem., 2007, 692, 4237.

    Article  CAS  Google Scholar 

  21. N. P. Kushwah, M. K. Pal, A. P. Wadawale, V. K. Jain, J. Organomet. Chem., 2009, 694, 2375.

    Article  CAS  Google Scholar 

  22. M. K. Pal, N. P. Kushwah, A. P. Wadawale, V. K. Jain, J. Chem. Res., 2010, 34, 485.

    Article  CAS  Google Scholar 

  23. N. Kushwah, M. K. Pal, A. Wadawale, V. Sudarsan, D. Manna, T. K. Ghanty, V. K. Jain, Organometallics, 2012, 31, 3836.

    Article  CAS  Google Scholar 

  24. N. P. Kushwah, M. K. Pal, A. P. Wadawale, V. K. Jain, Indian J. Chem., Sect. A, 2011, 50, 674.

    Google Scholar 

  25. S. Ghoshal, A. Wadawale, V. K. Jain, M. Nethaji, J. Chem. Res., 2007, 221.

    Google Scholar 

  26. M. K. Pal, N. Kushwah, D. Manna, A Wadawale, V. Sudarsan, T. K. Ghanty, V. K. Jain, Organometallics, 2013, 32, 104.

    Article  CAS  Google Scholar 

  27. S. Ghoshal, N. P. Kushwah, D. P. Dutta, V. K. Jain, Appl. Organomet. Chem., 2005, 19, 1257.

    Article  CAS  Google Scholar 

  28. S. Ghoshal, N. P. Kushwah, M. K. Pal, V. K. Jain, M. Nethaji, J. Chem. Sci., 2008, 120, 305.

    Article  CAS  Google Scholar 

  29. S. Ghoshal, V. K. Jain, D. P. Dutta, P. P. Phadnis, M. Nethaji, J. Organomet. Chem., 2006, 691, 5838.

    Article  CAS  Google Scholar 

  30. R. K. Sharma, G. Kedarnath, N. Kushwah, M. K. Pal, A. Wadawale, B. Vishwanadh, B. Paul, V. K. Jain, J. Organomet. Chem., 2013, 747, 113.

    Article  CAS  Google Scholar 

  31. S. Ghoshal, L. B. Kumbhare, V. K. Jain, G. K. Dey, Bull. Mater. Sci., 2007, 30, 173.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Division, Bhabha Atomic Research Centre, Mumbai, 400 085, India

    V. K. Jain, A. Wadawale, N. P. Kushwah & M. K. Pal

Authors
  1. V. K. Jain
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Wadawale
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. P. Kushwah
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. K. Pal
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. K. Jain.

Additional information

According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamentals and Applied Aspects” (September 1–7, 2013, Nizhniy Novgorod).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0781–0787, April, 2014.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jain, V.K., Wadawale, A., Kushwah, N.P. et al. Synthesis, structures and utility of organogallium and organoindium complexes with oxo and thio ligands. Russ Chem Bull 63, 781–787 (2014). https://doi.org/10.1007/s11172-014-0511-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-014-0511-0

Kew words

Search

Navigation