Abstract
Monodisperse 280–480 nm silica particles doped with europium complexes with thenoyltrifluoroacetylacetone and adducts with some phosphine oxides as luminophores were prepared for the first time by the optimized Stober procedure using surfactants. The size and the polydispersity of the obtained particles depend on the luminophore incorporated in the polymer template. The photophysical properties of aqueous dispersions of the europium(iii)-doped silica particles were studied by the luminescence method.
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M.-J. Li, Z. Chen, V. W.-W. Yam, Y. Zu, ACS Nano, 2008, 2, 905.
H. Wu, Q. Huo, S. Varnum, J. Wang, G. Liu, Z. Nie, J. Liu, Y. Lin, Analyst, 2008, 133, 1550.
I. Roy, T. Y. Ohulchaskyy, D. J. Bharali, H. E. Pudavar, R. A. Mistretta, N. Kaur, P. N. Prasad, PNAS, 2005, 102, 279.
Z. Ye, M. Tan, G. Wang, J. Yuan, Talanta, 2005, 65, 206.
F. Enrichi, R. Ricco, P. Scopece, A. Parma, A. R. Mazaheri, P. Riello, A. Benedetti, J. Nanopart. Res., 2010, 12, 1925.
F. Gao, F. Luo, X. Chen, W. Yao, J. Yin, Zh. Yao, L. Wang, Talanta, 2009, 80, 202.
H. Jiang, G. Wang, W. Zhang, X. Liu, Z. Ye, D. Jin, J. Yuan, Zh. Liu, J. Fluoresc., 2010, 20, 321.
K. Binnemans, P. Lenaerts, K. Driesen, Ch. Görller-Walrand, J. Mater. Chem., 2004, 14, 191.
Ch. Wu, J. Hong, X. Guo, Ch. Huang, J. Lai, J. Zheng, J. Chen, X. Mu, Y. Zhao, Chem. Commun., 2008, 750.
R. P. Bagwe, L. R. Hilliard, W. Tan, Langmuir, 2006, 22, 4357.
L.-S. Wang, L.-C. Wu, S.-Y. Lu, L.-L. Chang, I.-T. Teng, C.-M. Yang, J. A. Ho, ACS Nano, 2010, 4. 4371.
T. Perrier, P. Saulnier, J.-P. Benoot, Chem.-Eur. J., 2010, 16, 11516.
J. R. Lakowicz, Principles of fluorescence spectroscopy, Springer, 2006, 960.
S. Bonacchi, D. Genovese, R. Juris, E. Marzocchi, M. Montalti, L. Prodi, E. Rampazzo, N. Zaccheroni, Reviews in Fluorescence, Ed. C. D. Geddes, Springer, 2008, 119.
B. Chen, J. Xu, N. Dong, H. Liang, Q. Zhang, M. Yin, Spectrochim. Acta, Part A, 2004, 60, 3113.
H. Xu, W. Huang, J. Photochem. Photobiol. A: Chem., 2011, 217, 213.
H. Härmä, Ch. Graf, P. Hänninen, J. Nanopart. Res., 2008, 10, 1221.
A. R. Mustafina, S. V. Fedorenko, O. D. Konovalova, A. Yu. Menshikova, N. N. Shevchenko, S. E. Soloveva, A. I. Konovalov, I. S. Antipin, Langmuir, 2009, 25, 3146.
R. G. Charles, R. C. Ohlmann, J. Inorg. Nucl. Chem., 1965, 27, 255.
A. Mustafina, R. Zairov, M. Gruner, A. Ibragimova, D. Tatarinov, I. Nizameev, N. Nastapova, V. Yanilkin, M. Kadirov, V. Mironov, A. Konovalov, Colloids and Surfaces B: Biointerfaces, 2011, 88, 490.
RF Patent 2329271, Byul. Izobret., 2008, 20.
G. Orts-Gil, K. Natte, D. Drescher, G. Orts-Gil, H. Bresch, A. Mantion, J. Kneipp, W. Osterle, J. Nanopart. Res., 2011, 13, 1593.
D. R. Larson, H. Ow, H. D. Vishwasrao, A. A. Heikal, U. Wiesner, W. W. Webb, Chem. Mater., 2008, 20, 2677.
Z. Ye, M. Tan, G. Wang, J. Yuan, Talanta, 2005, 65, 206.
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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 80th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2180–2184, November, 2011.
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Fedorenko, S.V., Mustafina, A.R., Skripacheva, V.V. et al. Synthesis and photophysical properties of silica nanoparticles based on europium(iii) complexes. Russ Chem Bull 60, 2222–2226 (2011). https://doi.org/10.1007/s11172-011-0341-2
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DOI: https://doi.org/10.1007/s11172-011-0341-2