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Synthesis and properties of water-soluble silica nanoparticles

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Abstract

Methods for synthesis and optimum conditions of the formation of stable water-soluble silica nanoparticles are presented. The silica nanoparticles were synthesized by the hydrolytic polycondensation of tetraethoxysilane using two methods: under alkaline conditions (Stöber´s method) or in an acetic acid medium followed by the modification by grafting triethylene oxide moieties on the particle surface. The structure of the modified silica nanoparticles was confirmed by the data of IR and NMR spectroscopy. Polydispersity was evaluated by gel permeation chromatography and dynamic light scattering. The formation and stability of Langmuir monolayers of the silica nanoparticles modified by triethylene oxide moieties were studied.

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Authors and Affiliations

  1. N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    O. B. Gorbatsevich, D. N. Kholodkov, T. S. Kurkin, D. R. Strel’tsov, A. I. Buzin, V. V. Kazakova & A. M. Muzafarov

  2. A. N. Nesmeyanov of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. N. Kholodkov & A. M. Muzafarov

  3. Moscow Technological University, Institute of Fine Chemical Technologies, Russian Academy of Sciences, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    Yu. N. Malakhova

  4. National Research Centre “Kurchatov Institute”, 1 pl. Akad. Kurchatova, 123182, Moscow, Russian Federation

    Yu. N. Malakhova & D. R. Strel’tsov

Authors
  1. O. B. Gorbatsevich
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  2. D. N. Kholodkov
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  3. T. S. Kurkin
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  4. Yu. N. Malakhova
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  6. A. I. Buzin
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  7. V. V. Kazakova
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  8. A. M. Muzafarov
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Correspondence to V. V. Kazakova.

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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 70th birthday.

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Gorbatsevich, O.B., Kholodkov, D.N., Kurkin, T.S. et al. Synthesis and properties of water-soluble silica nanoparticles. Russ Chem Bull 66, 409–417 (2017). https://doi.org/10.1007/s11172-017-1748-1

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  • DOI: https://doi.org/10.1007/s11172-017-1748-1

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