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Reduction of the groups C=O and C=N with neodymium and dysprosium diiodide hydrides

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Abstract

Neodymium diiodide hydride under mild conditions adds at the carbonyl group of benzophenone to give (diphenylmethoxy)(diiodo)neodymium(iii) of the formula I2Nd(OCHPh2)(THF)4. In reactions of NdI2H and DyI2H with N-(2,6-diisopropylphenyl)-9,10-phenanthrenequinonimine, the system of conjugated C=N and C=O groups of the quinone is reduced. The resulting o-aminophenanthrolate complexes are structurally characterized by X-ray diffraction.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    M. E. Burin, A. A. Logunov, N. O. Druzhkov, G. K. Fukin & M. N. Bochkarev

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  1. M. E. Burin
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  2. A. A. Logunov
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  3. N. O. Druzhkov
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  4. G. K. Fukin
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  5. M. N. Bochkarev
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Correspondence to M. E. Burin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1562–1565, August, 2011.

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Burin, M.E., Logunov, A.A., Druzhkov, N.O. et al. Reduction of the groups C=O and C=N with neodymium and dysprosium diiodide hydrides. Russ Chem Bull 60, 1586–1590 (2011). https://doi.org/10.1007/s11172-011-0236-2

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  • DOI: https://doi.org/10.1007/s11172-011-0236-2

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