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1,2,3,4,7-Pentamethylindenyl complex [(η5-C9H2Me5)RhI2]2 as a synthon for the [(η5-C9H2Me5)Rh]2+ fragment

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Abstract

The reaction of the iodide complex [(η5-C9H2Me5)RhI2]2 (1) or the acetonitrile complex [(η5-C9H2Me5)Rh(MeCN)3]2+ with Tl[Tl(η-7,8-C2B9H11)] afforded rhodacarborane (η5-C9H2Me5)Rh(7,8-C2B9H11) (2). The cationic triple-decker complex with the bridging boratabenzene ligand [Cp*Fe(μ-η:η-C5H3Me2BMe)Rh(η5-C9H2Me5)]2+ (3) was synthesized by the reaction of the nitromethane solvate [(η5-C9H2Me5)Rh(MeNO2)3]2+ with the sandwich compound Cp*Fe(η-C5H3Me2BMe). The structure of 2 was established by X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, A. V. Vologzhanina, P. V. Petrovskii, M. M. Vinogradov & A. R. Kudinov

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  1. D. A. Loginov
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  2. A. V. Vologzhanina
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  3. P. V. Petrovskii
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  4. M. M. Vinogradov
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  5. A. R. Kudinov
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Correspondence to A. R. Kudinov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1623–1625, August, 2008.

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Loginov, D.A., Vologzhanina, A.V., Petrovskii, P.V. et al. 1,2,3,4,7-Pentamethylindenyl complex [(η5-C9H2Me5)RhI2]2 as a synthon for the [(η5-C9H2Me5)Rh]2+ fragment. Russ Chem Bull 57, 1653–1656 (2008). https://doi.org/10.1007/s11172-008-0215-4

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  • DOI: https://doi.org/10.1007/s11172-008-0215-4

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