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Construction of 18-electron arene-ruthenium complexes based on ortho-carborane-1,2-diselenolate ligand

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Abstract

Treatment of ortho-carborane, n-butyl lithium, selenium and [(p-cymene)RuCl2]2 under argon leads to complexes (p-cymene)Ru(Se2C2B10H10) (I) and (p-cymene)2Ru2(μ2-Se2C2B10H10) (II). The further reaction of 16-electron complex I with RC≡CCO2Me affords addition complexes (p-cymene)Ru(Se2C2B10H10)(RC=C-CO2Me) (III) (R = H (IIIa); CO2Me (IIIb)). These complexes were characterized by elemental analysis, mass, and NMR spectroscopy. X-ray structural analyses were performed on II and IIIa.

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Authors and Affiliations

  1. Key Laboratory of Applied Organic Chemistry, Higher Institutions of Jiangxi Province, School of Chemistry and Chemical Engineering, Shangrao Normal University, Jiangxi, 334001, China

    J. R. Hu, H. D. Ye, Y. H. Wang & F. Y. Chen

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  1. J. R. Hu
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  2. H. D. Ye
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  3. Y. H. Wang
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  4. F. Y. Chen
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Correspondence to J. R. Hu.

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Hu, J.R., Ye, H.D., Wang, Y.H. et al. Construction of 18-electron arene-ruthenium complexes based on ortho-carborane-1,2-diselenolate ligand. Russ J Coord Chem 40, 413–418 (2014). https://doi.org/10.1134/S1070328414060013

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  • DOI: https://doi.org/10.1134/S1070328414060013

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