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Reduction of (1,3-diformylindenyl)cyclopentadienylruthenium derivatives

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Abstract

The reduction of the (1,3-diformylindenyl)cyclopentadienylruthenium derivatives {η5-1,3-(CHO)2C9H5}RuCp (Cp = C5H5), {η5-1,3-(CHO)2C9H5}RuCp* (Cp* = C5Me5), and {η5-1,3-(CHO)2C9H5}RuCpF (CpF = C5Me4CF3) with NaBH4 or LiAlH4 under mild conditions affords the [1,3-bis(hydroxymethyl)indenyl]cyclopentadienylruthenium complexes {η5-1,3-(CH2OH)2C9H5}RuCp, {η5-1,3-(CH2OH)2C9H5}RuCp*, and {η5-1,3-(CH2OH)2C9H5}-RuCpF, respectively, in good yields.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. V. Safronov, S. A. Kuklin, A. M. Sheloumov & A. A. Kamyshova

  2. Institute of Organometallic Chemistry, I. Javakhishvili Tbilisi State University, 3 Chavchavadze Avenue, 0128, Tbilisi, Georgia

    A. A. Koridze

Authors
  1. S. V. Safronov
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  2. S. A. Kuklin
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  3. A. M. Sheloumov
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  4. A. A. Kamyshova
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  5. A. A. Koridze
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Correspondence to S. V. Safronov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0033—0035, January, 2018.

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Safronov, S.V., Kuklin, S.A., Sheloumov, A.M. et al. Reduction of (1,3-diformylindenyl)cyclopentadienylruthenium derivatives. Russ Chem Bull 67, 33–35 (2018). https://doi.org/10.1007/s11172-018-2033-7

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  • DOI: https://doi.org/10.1007/s11172-018-2033-7

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