Abstract
Three new mixed tellurides of nickel and group 13–14 metals Ni3−δMTe2 (M = Sn, In, Ga) were prepared by high-temperature ampoule synthesis and studied by powder X-ray diffraction analysis. The compound Ni3−δSnTe2 was also studied by single crystal X-ray diffraction analysis. The structural model of this phase and two analogs was described as consisting of layers with nickel-main group metal bonds confined from the above by tellurium atoms. The van der Waals gap formed through contacts between the tellurium atoms of neighboring layers is partially occupied by nickel atoms.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
A. I. Baranov, A. A. Isaeva, L. Kloo, and B. A. Popovkin, Inorg. Chem., 2003, 42, 6667.
T. K. Reynolds, J. G. Bales, and F. J. DiSalvo, Chem. Mater., 2002, 14, 4746.
A. A. Isaeva, A. I. Baranov, Th. Doert, B. A. Popovkin, V. A. Kulbachinskii, P. V. Gurin, V. G. Kytin, and V. I. Shtanov, J. Solid State Chem., 2007, 180, 221.
T. K. Reynolds, R. F. Kelley, and F. J. DiSalvo, J. Alloys Comp., 2004, 366, 136.
H.-J. Deiseroth, K. Aleksandrov, C. Reiner, L. Kienle, and R. K. Kremer, Eur. J. Inorg. Chem., 2006, 1561.
G. M. Sheldrick, SHELX-97, Program Package for Crystal Structure Solution and Refinement, Göttingen, Germany, 1997.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1879–1881, October, 2007.
Rights and permissions
About this article
Cite this article
Litvinenko, O.N., Kuznetsov, A.N., Olenev, A.V. et al. New mixed tellurides of nickel and Group 13–14 metals Ni3−δMTe2 (M = Sn, In, Ga). Russ Chem Bull 56, 1945–1947 (2007). https://doi.org/10.1007/s11172-007-0301-z
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-007-0301-z