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New trigonal tris(phosphine oxides)

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Abstract

The reaction of 1,1,1-tris(chloromethyl)propane with diphenylphosphine under phase-transfer conditions afforded 1,1,1-tris(diphenylphosphinomethyl)propane, whose oxidation gave a previously unknown representative of trigonal tris(phosphine oxides), viz., stable 1,1,1-tris(diphenylphosphorylmethyl)propane. Its analogs, viz., bis(diphenylphosphoryl)diphenylphosphinomethane and tris(diphenylphosphoryl)methane, are unstable in air and decompose with the cleavage of the P-C bond.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. A. Pisareva, P. V. Petrovskii, K. A. Lyssenko, M. Yu. Antipin & E. E. Nifant’ev

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  1. S. A. Pisareva
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  2. P. V. Petrovskii
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  3. K. A. Lyssenko
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  4. M. Yu. Antipin
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  5. E. E. Nifant’ev
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1926–1929, September, 2004.

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Pisareva, S.A., Petrovskii, P.V., Lyssenko, K.A. et al. New trigonal tris(phosphine oxides). Russ Chem Bull 53, 2008–2012 (2004). https://doi.org/10.1007/s11172-005-0063-4

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  • DOI: https://doi.org/10.1007/s11172-005-0063-4

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