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Unsymmetrical Tripodal Phosphine Oxide with Triazole Groups: Synthesis and Molecular Structure

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Abstract

The Mitsunobu reaction of tris(2-hydroxyphenyl)phosphine oxide with 3-butyn-1-ol has afforded bis[2-(3′′-butynyloxy)phenyl](2′-hydroxyphenyl)phosphine oxide, which has been converted into the corresponding triazole via click reaction with PhN3. Asymmetric tripodal ligand containing three 1,2,3-triazole groups in the molecule has been prepared from this triazole via the reaction with propargyl bromide and PhN3. Structure of the ligand has been elucidated by means of single-crystal X-ray diffraction analysis.

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Funding

This study was financially supported by the Russian Science Foundation (grant no. 20-13-00329). Elemental analysis, registration of NMR, IR, and Raman spectra, and X-ray diffraction analysis were supported by the Ministry of Science and Higher Education of the Russian Federation and performed using the research equipment of the Center for Study of Molecular Structure, Institute of Organoelement Compounds, RAS.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    O. V. Bykhovskaya, I. Yu. Kudryavtsev, T. V. Baulina, M. P. Pasechnik, A. V. Vologzhanina, A. G. Matveeva, A. A. Moiseeva & V. K. Brel

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  1. O. V. Bykhovskaya
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  2. I. Yu. Kudryavtsev
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  3. T. V. Baulina
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  4. M. P. Pasechnik
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  5. A. V. Vologzhanina
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  6. A. G. Matveeva
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  8. V. K. Brel
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Correspondence to I. Yu. Kudryavtsev.

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V. K. Brel is a member of Editorial Board of the Russian Journal of General Chemistry. Other authors declare that they have no conflicts of interest.

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Bykhovskaya, O.V., Kudryavtsev, I.Y., Baulina, T.V. et al. Unsymmetrical Tripodal Phosphine Oxide with Triazole Groups: Synthesis and Molecular Structure. Russ J Gen Chem 92, 1420–1429 (2022). https://doi.org/10.1134/S1070363222080084

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