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Concentration Effect in Copolymerization of Sodium 2-Acrylamido-2-methylpropanesulfonate with N-Vinylpyrrolidone in Aqueous Solutions

  • Macromolecular Chemistry and Polymeric Materials
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Abstract

The kinetics of copolymerization of sodium 2-acrylamido-2-methylpropanesulfonate with N-vinyl-pyrrolidone in aqueous solutions in the presence of potassium persulfate at 40 – 70°C and the molecular characteristics of the resulting complexes were studied, as influenced by the total concentration of the initial monomer mixture, comonomer ratio, temperature, and conversion. The kinetic data were explained taking into account the state of the ionic groups, electrostatic interactions between the reacting particles, and complexation of comonomers in the course of copolymerization.

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Authors and Affiliations

  1. Kazan State Technological University, Kazan, Tatarstan, Russia

    V. F. Kurenkov, T. A. Zhelonkina & V. I. Kovalenko

Authors
  1. V. F. Kurenkov
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  2. T. A. Zhelonkina
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  3. V. I. Kovalenko
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Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 2, 2005, pp. 301–305.

Original Russian Text Copyright © 2005 by Kurenkov, Zhelonkina, Kovalenko.

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Kurenkov, V.F., Zhelonkina, T.A. & Kovalenko, V.I. Concentration Effect in Copolymerization of Sodium 2-Acrylamido-2-methylpropanesulfonate with N-Vinylpyrrolidone in Aqueous Solutions. Russ J Appl Chem 78, 295–300 (2005). https://doi.org/10.1007/s11167-005-0278-z

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  • DOI: https://doi.org/10.1007/s11167-005-0278-z

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