Skip to main content
SpringerLink
Log in

The copolymer coating effect on the catalytic activity of magnetic carbon nanotube (CNT-Fe3O4) in the multi-component reactions

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

Two new magnetic nanocomposites containing aniline–pyrrole copolymer-coated magnetic carbon nano-tubes (poly(Ani-co-Py)@CNT-Fe3O4) were synthesized and characterized by Fourier transform infrared (FT-IR) spectroscopy, energy-dispersive X-ray analysis (EDS), scanning electron microscopy (SEM) and vibrating-sample magnetometer (VSM) techniques. The catalytic activity of poly(Ani-co-Py)@CNT-Fe3O4 nanocomposites was investigated in the multi-component preparation of 2′-aminospiro[indeno[1,2-b]quinoxaline-11,4′-[4′H]pyran]-3′-carbonitrile and 2′-aminospiro[indeno-2,4′-[4′H]pyran]-3′-carbonitrile derivatives. The reusability of these nanocomposites was also studied and compared together. High efficiency, reusability, non-toxicity, stability and magnetic separation of the catalyst in combination with short reaction time, high product yield, easy work-up procedure, high purity of the product are noteworthy advantages of the current methods.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Scheme 1.
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Scheme 2
Scheme 3
Scheme 4

Similar content being viewed by others

References

  1. M.M.J. Treacy, T.W. Ebbesen, J.M. Gibson, Nature 381, 678 (1996)

    Article  CAS  Google Scholar 

  2. M.F. Yu, O. Lourie, M.J. Dyer, K. Moloni, T.F. Kelly, R.S. Ruoff, Science 287, 637 (2000)

    Article  CAS  PubMed  Google Scholar 

  3. L. Wu, L. Sun, X. Li, Q. Zhang, H. Si, Y. Zhang, K. Wang, Y. Zhang, Appl Surf Sci 506, 144964 (2020)

    Article  CAS  Google Scholar 

  4. M.S. Mauter, M. Elimelech, Environ. Sci. Technol. 42, 5843 (2008)

    Article  CAS  PubMed  Google Scholar 

  5. J.G. Wang, H. Liu, X. Zhang, X. Li, X. Liu, F. Kang, Small 14, 1703950 (2018)

    Article  Google Scholar 

  6. H.C. Wu, X. Chang, L. Liu, F. Zhao, Y. Zhao, J. Mater. Chem. 20, 1036 (2010)

    Article  CAS  Google Scholar 

  7. A. Abdar, A. Sarafraz-Yazdi, A. Amiri, N. Bagheri, J. Sep. Sci. 39, 2746 (2016)

    Article  CAS  PubMed  Google Scholar 

  8. Y. Yan, J. Miao, Z. Yang, F. Xiao, H. Yang, B. Liu, Y. Yang, Chem Soc Rev 44, 3295 (2015)

    Article  CAS  PubMed  Google Scholar 

  9. M. Kuhara, H. Takeyama, T. Tanaka, T. Matsunaga, Anal. Chem. 76, 6207 (2004)

    Article  CAS  PubMed  Google Scholar 

  10. M.F. Horst, V. Lassalle, M.L. Ferreira, Front. Env. Sci. Eng. 9, 746 (2015)

    Article  CAS  Google Scholar 

  11. R.Y. Hong, B. Feng, L.L. Chen, G.H. Liu, H.Z. Li, Y. Zheng, D.G. Wei, Biochem. Eng. J. 42, 290 (2008)

    Article  CAS  Google Scholar 

  12. I.J. Bruce, J. Taylor, M. Todd, M.J. Davies, E. Borioni, C. Sangregorio, T. Sen, J. Magn. Magn. Mater. 284, 145 (2004)

    Article  CAS  Google Scholar 

  13. X. Liu, Y. Guan, Z. Ma, H. Liu, Langmuir 20, 10278 (2004)

    Article  CAS  PubMed  Google Scholar 

  14. S.F. Hojati, A. Amiri, N. MoeiniEghbali, S. Mohamadi, Appl. Organomet. Chem. 32, e4235 (2018)

    Article  Google Scholar 

  15. S.F. Hojati, A. Amiri, S. Mohamadi, N. MoeiniEghbali, Res. Chem. Intermed. 44, 2275 (2018)

    Article  CAS  Google Scholar 

  16. Ch. Li, J. Sun, D. Chen, G. Han, Sh. Yu, Sh. Kang, L. Mei, J. Nanomat. 16, 1 (2016)

    Google Scholar 

  17. P.B. Koli, K.H. Kapadnis, U.G. Deshpande, J. Environ. Chem. Eng. 7, 103373 (2019)

    Article  CAS  Google Scholar 

  18. U. Lange, N.V. Roznyatovskaya, V.M. Mirsky, Anal. Chim. Acta. 614, 1 (2008)

    Article  CAS  PubMed  Google Scholar 

  19. M. Tebyetekerwa, X. Wang, Y. Wu, Sh. Yang, M. Zhu, S. Ramakrishna, J. Mat. Chem. A 5, 21114 (2017)

    Article  CAS  Google Scholar 

  20. M. Tebyetekerwa, S. Yang, S. Peng, Z. Xu, W. Shao, D. Pan, S. Ramakrishna, M. Zhu, Electrochim. Acta 247, 400 (2017)

    Article  CAS  Google Scholar 

  21. P.G. Wyatt, B.A. Coomber, D.N. Evans, T.I. Jack, H.E. Fultion, A.J. Wonacott, P. Colman, J. Varghese, J. Bioorg. Med. Chem. Lett. 11, 669 (2001)

    Article  CAS  Google Scholar 

  22. A. Kumar, R.A. Maurya, S. Sharma, P. Ahmad, A.B. Singh, G. Bhatia, A.K. Srivastava, Bioorg. Med. Chem. Lett. 19, 6447 (2009)

    Article  CAS  PubMed  Google Scholar 

  23. J.Y.C. Wu, W.F. Fong, J.X. Zhang, C.H. Leung, H.L. Kwong, M.S. Yang, D. Li, H.Y. Cheung, Eur. J. Pharmacol. 473, 9 (2003)

    Article  CAS  PubMed  Google Scholar 

  24. A.R. Saundane, K. Vijaykumar, A.V. Vaijinath, Bioorg. Med. Chem. Lett. 23, 1978 (2013)

    Article  CAS  PubMed  Google Scholar 

  25. L. Chen, X.J. Huang, Y.Q. Li, M.Y. Zhou, W.J. Zheng, Monatsh. Chem. 14, 45 (2009)

    Article  Google Scholar 

  26. C.V. Rao, A. Rivenson, B. Simi, E. Zang, G. Kelloff, V. Steele, B.S. Reddy, Cancer Res. 55, 1464 (1995)

    CAS  PubMed  Google Scholar 

  27. A.C. Spyropoulos, K.A. Hayth, P. Jenkins, Pharmacotherapy 23, 533 (2003)

    Article  PubMed  Google Scholar 

  28. T.B. Hadda, F.Z. Khardli, M. Mimouni, M. Daoudi, A. Kerbal, H. Salgado-Zamora, N. Gandhare, A. Parvez, S. Lahsasni, Phosphorus Sulfur Silicon Relat. Elem. 189, 753 (2014)

    Article  Google Scholar 

  29. K.S. Mani, W. Kaminsky, S.P. Rajendran, New J. Chem. 42, 301 (2018)

    Article  Google Scholar 

  30. W. Gu, S. Wang, X. Jin, Y. Zhang, D. Hua, T. Miao, X. Tao, S. Wang, Molecules 22, 1154 (2017)

    Article  PubMed Central  Google Scholar 

  31. G. Bhaskar, Y. Arun, C. Balachandran, C. Salikumar, P.T. Perumal, Eur. J. Med. Chem. 51, 79 (2012)

    Article  CAS  PubMed  Google Scholar 

  32. Y.T. Yang, J.F. Zhu, G. Liao, H.J. Xu, B. Yu, Curr. Med. Chem. 25, 2233 (2018)

    Article  CAS  PubMed  Google Scholar 

  33. Y. Arun, G. Bhaskar, C. Balachandran, S. Ignachimuthu, P.T. Perumal, Bioorg. Med. Chem. Lett. 23, 1839 (2013)

    Article  CAS  PubMed  Google Scholar 

  34. A.S. Girgis, Eur. J. Med. Chem. 44, 91 (2009)

    Article  CAS  PubMed  Google Scholar 

  35. E. Rajaranendar, K. Ramakrishna, K. Govardhan Reddy, D. Nagaraju, N.Y. Reddy, Bioorg. Med. Chem. Lett. 23, 3954 (2013)

    Article  Google Scholar 

  36. K.I. Molvi, N. Haque, B.Z. Awen, M. Zameeruddin, World. J. Pharm. Sci. 3, 536 (2014)

    Google Scholar 

  37. A.S. Girgis, Eur. J. Med. Chem. 44, 1257 (2009)

    Article  CAS  PubMed  Google Scholar 

  38. S.R.G. Venkata, U.C. Narkhede, V.D. Jadhav, N. Gangu, Y. Bobde, B. Ghosh, Chem. Select 3, 12139 (2018)

    CAS  Google Scholar 

  39. A. Hasaninejad, N. Golzar, A. Zare, J. Heterocycl. Chem. 50, 608 (2013)

    Article  CAS  Google Scholar 

  40. A. Hasaninejad, N. Golzar, M. Shekouhy, M. Zare, Chim. Acta. 94, 2289 (2011)

    Article  CAS  Google Scholar 

  41. F. Chen, J. Zheng, M. Huang, Y. Li, Res. Chem. Intermed. 41, 5545 (2015)

    Article  CAS  Google Scholar 

  42. M.R. Poor Heravi, F. Norouzy, Res. Chem. Intermed. 43, 4265 (2017)

    Article  CAS  Google Scholar 

  43. S.F. Hojati, A. Amiri, E. Fardi, Appl. Organomet. Chem. 34, e5604 (2020)

    Article  CAS  Google Scholar 

  44. S.F. Hojati, A. Amiri, M. Mahamed, Res. Chem. Intermed. 46, 1091 (2020)

    Article  CAS  Google Scholar 

  45. S.H. Hojati, A. Amiri, H. Raouf, Appl. Organomet. Chem. 31, e3595 (2017)

    Article  Google Scholar 

  46. S.F. Hojati, N. MoeiniEghbali, S. Mohamadi, T. Ghorbani, Org. Prep. Proced. Int. 50, 408 (2018)

    Article  CAS  Google Scholar 

  47. S.F. Hojati, M. Moosavifar, T. Ghorbanipoor, CR Chemie 20, 520 (2017)

    Article  CAS  Google Scholar 

  48. M. Keshavarz, M. Abdoli-Senejani, S.F. Hojati, S. Askari, React. Kinet. Mech. Catal. 124, 757 (2018)

    Article  CAS  Google Scholar 

  49. S.F. Hojati, H. Raouf, Org. Prep. Proced. Int. 48, 474 (2016)

    Article  CAS  Google Scholar 

  50. M. Khairy, J. Alloys Compd. 608, 283 (2014)

    Article  CAS  Google Scholar 

  51. M. Shanehsaz, S. Seidi, Y. Ghorbani, S.M. Shoja, S. Rouhani, Spectrochim. Acta A; Mol Biomol. Spectrosc. 149, 481 (2015)

    Article  CAS  PubMed  Google Scholar 

  52. P. Saluja, K. Aggarwal, J.M. Khurana, Synth. Commun. 43, 3239 (2013)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Authors gratefully acknowledge the Hakim Sabzevari University for financial support of this work.

Author information

Authors and Affiliations

  1. Department of Chemistry, Hakim Sabzevari University, Sabzevar, 96179-76487, Iran

    Seyedeh Fatemeh Hojati, Elham Fardi & Maryam Mahamed

  2. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, 9177948974, Iran

    Amirhassan Amiri

Authors
  1. Seyedeh Fatemeh Hojati
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Amirhassan Amiri
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Elham Fardi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Maryam Mahamed
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Seyedeh Fatemeh Hojati.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hojati, S.F., Amiri, A., Fardi, E. et al. The copolymer coating effect on the catalytic activity of magnetic carbon nanotube (CNT-Fe3O4) in the multi-component reactions. Res Chem Intermed 48, 1347–1363 (2022). https://doi.org/10.1007/s11164-022-04663-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-022-04663-3

Keywords

Search

Navigation