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Zeolite ZSM-11 as a reusable and efficient catalyst promoted improved protocol for synthesis of 2,4,5-triarylimidazole derivatives under solvent-free condition

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Abstract

Zeolite ZSM-11 catalyst was prepared by hydrothermal method and characterized by FTIR, XRD, SEM, HRTEM, EDS, and BET analysis techniques. The catalyst shows good catalytic activity toward synthesis of 2,4,5-triarylimidazole derivatives which is prepared by using benzil, aldehyde and ammonium acetate in solvent-free condition. The reaction, one pot synthesis is highly adaptable and eco-friendly and has several merits such as short reaction time, mild reaction conditions, and high yield. The ease of reusability and recovery of catalyst for five consecutive reactions makes this protocol highly suitable.

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Acknowledgements

One of the authors, Mr. Sudarshan S. Dipake, gratefully thankful to the Council of Scientific and Industrial Research (CSIR), New Delhi for the award of fellowship and to the Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad-431004 (M.S.), India. for support and providing the necessary laboratory facility.

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Authors and Affiliations

  1. Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, Maharashtra, 431004, India

    Sudarshan S. Dipake, Machhindra K. Lande, Anjali S. Rajbhoj & Suresh T. Gaikwad

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  1. Sudarshan S. Dipake
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  2. Machhindra K. Lande
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  3. Anjali S. Rajbhoj
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  4. Suresh T. Gaikwad
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Contributions

SSD-Conduct the whole experiment, Writing original draft. MKL-Review and editing. ASR-Review and editing. STG-Principal author.

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Correspondence to Suresh T. Gaikwad.

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Dipake, S.S., Lande, M.K., Rajbhoj, A.S. et al. Zeolite ZSM-11 as a reusable and efficient catalyst promoted improved protocol for synthesis of 2,4,5-triarylimidazole derivatives under solvent-free condition. Res Chem Intermed 47, 2245–2261 (2021). https://doi.org/10.1007/s11164-021-04423-9

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