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TS-1 zeolite as a Lewis acid catalyst for solvent-free one-pot synthesis of 1,3-thiazolidin-4-ones

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Abstract

Titanium silicate (TS-1) zeolite heterogeneous catalyst is synthesized by the hydrothermally discontinuous method and is characterized by using XRD, SEM, TEM, and NH3–TPD techniques. The catalytic activity of the TS-1 type zeolite was tested for one-pot solvent-free synthesis of 1,3-thiazolidine-4-ones. The present technique illustrates many benefits, including eco-friendly reaction conditions, environmentally helpful, short response time, simplicity, straightforward separatation, catalyst reusability and high yields of the products. Furthermore, the catalyst was utilized for four recycle reactions and it has been found that the catalyst shows consistent chemical process activity.

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Acknowledgements

We are grateful to the head of the Department of Chemistry, Dr. B.A.M., University, Aurangabad, 431004 (MS), India for providing the laboratory facility. The corresponding author MKL is thankful to UGC New Delhi (INDIA) for providing grant under major research Project Funding No. 43-184/2014 (SR). The authors are thankful to STIC Cochin and SAIF Chandigarh, IIT Madras (Department of Chemistry), CDRI Lucknow characterization facilities.

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  1. Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad, Maharashtra, 431004, India

    Sachin P. Gadekar & Machhindra K. Lande

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  1. Sachin P. Gadekar
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  2. Machhindra K. Lande
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Correspondence to Machhindra K. Lande.

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Gadekar, S.P., Lande, M.K. TS-1 zeolite as a Lewis acid catalyst for solvent-free one-pot synthesis of 1,3-thiazolidin-4-ones. Res Chem Intermed 45, 237–247 (2019). https://doi.org/10.1007/s11164-018-3599-2

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