Abstract
This work deals with the preparation of MAPO-5 zeolite by a hydrothermal method. In order to study the adsorption properties of this zeolite several transition metals (Fe, Co, Ni, Mn and Zn) were incorporated by a direct route. The obtained zeolites were characterized by various physico-chemical techniques such as X-ray diffraction, Fourier transform infrared spectroscopy, adsorption/desorption of argon, thermogravimetric analysis/differential thermal analysis, scanning electronic microscopy (FEG-ESEM) and Inductively coupled plasma–optical Emission spectrometry (ICP-OES). The prepared zeolites were tested for adsorption of water and xylene isomers (ortho-, para- and meta-xylene). The obtained results showed that the isomorphic substitution of the transition metals in the framework of the zeolite has been achieved with different levels of metals. The isomorphic substitution by zinc showed the best results in terms of the percentage of the incorporated metal, while the substitution by cobalt presented the lowest rate of incorporation in the framework of the zeolite CoAPO-5. The adsorption of water in the vapor state on the zeolite substituted by Ni, Fe and Zn has presented the best adsorption capacity. The adsorption of xylene isomers on MAPO-5 showed different isotherms, confirming that the adsorption behavior differs from one zeolite to another. ZnAPO-5 showed higher adsorption capacity for all xylene isomers with slight selectivity towards meta-xylene.
Similar content being viewed by others
References
M. Polisi, R. Arletti, S. Quartieri, L. Pastero, C. Giacobbe, G. Vezzalini, Microporous Mesoporous Mater. 261, 137 (2018)
T. Gibbs, C.L.I.M. White, A.R. Ruiz-Salvador, D.W. Lewis, Stud. Surf. Sci. Catal. 154, 1737 (2004)
N. Djeffal, M. Benbouzid, B. Boukoussa, H. Sekkiou, A. Bengueddach, Mater. Res. Express. 4, 035504 (2017)
I. Terrab, B. Boukoussa, R. Hamacha, N. Bouchiba, R. Roy, A. Bengueddach, A. Azzouz, Thermochim. Acta 624, 95 (2016)
C. Wan, S. Ding, C. Zhang, X. Tan, W. Zou, X. Liu, X. Yang, Sep. Purif. Technol. 180, 1 (2017)
J. Grand, S.N. Talapaneni, A. Vicente, C. Fernandez, E. Dib, H.A. Aleksandrov, G.N. Vayssilov, R. Retoux, P. Boullay, J.P. Gilson, V. Valtchev, S. Mintova, Nat. Mater. 16, 1010 (2017)
S.N. Talapaneni, J. Grand, S. Thomas, H.A. Ahmad, S. Mintova, Mater. Des. 99, 574 (2016)
A. Hakiki, B. Boukoussa, Z. Kibou, I. Terrab, K. Ghomari, N. Choukchou-Braham, R. Hamacha, A. Bengueddach, A. Azzouz, Thermochim. Acta 662, 108 (2018)
A. Kessouri, B. Boukoussa, A. Bengueddach, R. Hamacha, Res. Chem. Intermed. 44, 2475 (2018)
S. Bellatreche, A. Hasnaoui, B. Boukoussa, J. Garcia-Aguilar, A. Berenguer-Murcia, D. Cazorla-Amoros, A. Bengueddach, Res. Chem. Intermed. 42, 8039 (2016)
S.-T. Wilson, B.-M. Lok, C.-A. Messina, T.-R. Cannan, E.-M. Flanigen, J. Am. Chem. Soc. 104, 1146 (1982)
J. Kornatowski, G. Zadrozna, J. Wloch, M. Rozwadowski, Langmuir 15, 5863 (1999)
C. Baerlocher, W.-M. Meier, D.-H. Olson, Atlas of Zeolite framework types. Elsevier, Amsterdam (2001)
S.-B. Waghmode, Y. Saha, Y. Kubota, Catal J. 228, 192 (2004)
M. Hartmann, L. Kevan, Chem. Rev. 99, 635 (1999)
B.M. Weckhuysen, R.R. Ramachandra, J.A. Martens, R.A. Schoonheydt, Eur. J. Inorg. Chem. 1999, 565 (1999)
E.-M. Flanigen, B.-M. Lok, R.-L. Patton, S.-T. Wilson, Stud. Surf. Sci. Catal. 28, 103 (1986)
M. Shafiei, M.-S. Alivand, A. Ali, A. Rashidi, D. Samimi, D. Mohebbi-Kalhori, Chem. Eng. J. 341, 164 (2018)
X. Zhang, B. Gao, A. Elise Creamer, C. Cao, Y. Li, J. Hazard. Mater. 338, 102 (2017)
K. Machowski, P. Kuśtrowski, B. Dudek, M. Michalik, Mater. Chem. Phys. 165, 253 (2015)
M. Kraus, U. Trommler, F. Holzer, F.-D. Kopinke, U. Roland, Chem. Eng. J. 351, 356 (2018)
M.G. Uytterhoeven, R.A. Schoonheydt, Microporous Mater. 3, 265 (1994)
B. Feng, J. Li, X. Zhu, Q. Guo, W. Zhang, G. Wen, Z. Zhang, L. Gu, Z. Yang, Q. Zhang, B. Shen, Catal. Today 263, 91 (2016)
A.X.S. Bruker, TOPAS V6: Genereal Profile and Structure Analysis Software for Powder Diffraction Data—User’s Manual (Bruker AXS, Karlsruhe, 2017)
S. Lowell, J.E. Shields, M.A. Thomas, M. Thommes. Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density. Springer, Berlin, p. 347 (2006)
S. Brunauer, P.H. Emmett, E. Teller, J. Am. Chem. Soc. 60, 309 (1938)
L. Zhou, J. Xu, C. Chen, F. Wang, X. Li, J. Porous Mater. 15, 7 (2008)
C. Coutanceau, J.-M. Da Silva, M.-F. Alvarez, F.-R. Ribeiro, M. Guisnet, J. Chim. Phys. 94, 765 (1997)
B.-W. Lu, H. Jon, T. Kanai, Y. Oumi, K. Itabashi, T. Sano, J. Mater. Sci. 41, 1861 (2001)
A. Corma, L.-T. Nemeth, M. Renz, S. Valencia, Nature 412, 423 (2001)
D. Yiyuan Khoo, H. Awala, S. Mintova, E.-P. Ng, Microporous Mesoporous Mater. 194, 200 (2014)
E.-P. Ng, S. Mintova, Microporous Mesoporous Mater. 114, 1 (2008)
J. Kornatowski, C. R. Chimie. 8, 561 (2005)
M. Amiri, S. Sohrabnezhad, A. Rahimi, Mater. Sci. Eng. C 37, 342 (2014)
G. Müller, J. Bódis, J. Kornatowski, Microporous Mesoporous Mater. 69, 1 (2004)
D.-D. Rosenfeld, D.-M.D. Barthomeuf, US Exxon Chem Pat. 4, 482 (1983)
A.S.T. Chiang, C.K. Lee, Z.H. Chang, Zeolites 11, 380 (1991)
J. Liu, M. Dong, Z. Sun, Z. Qin, J. Wang, Colloids Surf. A Physicochem. Eng. Aspects. 247, 41 (2004)
G. Lischke, B. Parlitz, U. Lohse, E. Schreier, R. Fricke, Appl. Catal. A 166, 351 (1998)
S. Gopalakrishnan, K.R. Viswanathan, S. Vishnu Priya, J. Herbert Mabel, M. Palanichamy, V. Murugesan, Catal. Commun. 10, 23 (2008)
V.R. Vijayaraghavan, K. Joseph Antony Raj, J. Mol, J. Mol. Catal. A Chem. 207, 41 (2004)
R. Wendelbo, R. Roque-Malherbe, Microporous Mater. 10, 23 (1997)
Z. Wu, Y. Yang, B. Tu, P.A. Webley, D. Zhao, Adsorption 15, 123 (2009)
A.M. Dehkordi, M. Khademi, Microporous Mesoporous Mater. 172, 136 (2013)
S. Tourani, M. Baghalha, F. Khorasheh, A. Behvandi, Fluid Phase Equilib. 298, 54 (2010)
Z.Y. Gu, D.Q. Jiang, H.F. Wang, X.Y. Cui, X.P. Yan, J. Phys. Chem. C 114, 311 (2010)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Moulai, S., Ghezini, R., Hasnaoui, A. et al. Adsorption behavior of water and xylene isomers on AlPO-5 zeolite modified by different transition metals. Res Chem Intermed 45, 1653–1668 (2019). https://doi.org/10.1007/s11164-018-3692-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11164-018-3692-6