Abstract
Hierarchical ZSM-5 zeolite has been successfully synthesized from rice husk ash by a facile and solvent-free method. The obtained samples were characterized by X-ray diffraction, X-ray fluorescence, scanning electron microscopy, magic angle spinning nuclear magnetic resonance, X-ray photoelectron spectroscopy, ultraviolet raman spectroscopy, thermogravimetric analysis–differential scanning calorimetry, Brunauer–Emmett–Teller (BET) analysis and temperature-programmed desorption of ammonia. The influences of synthesis time on ZSM-5 crystal growth and ZSM-5 zeolite properties were evaluated. The results suggested that the ZSM-5 synthesis process was solid-phase conversion and the crystallization was accomplished within 72 h at 150 °C. The Si, Al and Fe are tetrahedral coordinated and minute quantities of non-framework octahedral coordinated aluminium exist in synthetic ZSM-5, and it has weak and strong acid sites. The resultant ZSM-5 aggregates exhibited well-defined crystallinity and porosity, and possessed micro-/mesoporous structures. The BET surface area of the synthetic ZSM-5 zeolite was 308.41 m2/g, slightly less than that synthesized from a hydrothermal approach (320.69 m2/g). Moreover, this hierarchically porous ZSM-5 zeolite show a high-hierarchy factor up to 0.18. The proposed synthetic route in this work provides novel green alternative for the synthesis of hierarchical ZSM-5 zeolite from rice husk ash.
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References
A. Corma, Chem. Rev. 95, 559 (1995)
M.V. Parfenov, S.E. Malykhin, L.V. Pirutko, A.S. Kharitonov, E.V. Starokon, Res. Chem. Intermed. 41, 8735 (2015)
M.E. Davis, Nature 417, 813 (2002)
C.S. Cundy, P.A. Cox, Chem. Rev. 103, 663 (2003)
M. Saeidi, M. Hamidzadeh, Res. Chem. Intermed. 43, 2143 (2017)
Z. Song, Q. Zhang, P. Ning, X. Liu, J. Zhang, Y. Wang, L. Xu, Z. Huang, Res. Chem. Intermed. 42, 7429 (2016)
L. Ma, H. Qu, J. Zhang, Q. Tang, S. Zhang, Q. Zhong, Res. Chem. Intermed. 39, 4109 (2013)
F. Rezaei, P. Webley, Sep. Purif. Technol. 70, 243 (2010)
K. Egeblad, C.H. Christensen, M. Kustova, C.H. Christensen, Chem. Mater. 20, 946 (2008)
H.X. Tao, H. Yang, X.H. Liu, J.W. Ren, Y.Q. Wang, G.Z. Lu, Chem. Eng. J. 225, 686 (2013)
H.B. Zhang, Y.C. Ma, K.S. Song, Y.H. Zhang, Y. Tang, J. Catal. 302, 115 (2013)
Y.M. Jia, J.W. Wang, K. Zhang, W. Feng, S.B. Liu, C.M. Ding, P. Liu, Microporous Mesoporous Mater. 247, 103 (2017)
J.J. Ding, H.Y. Liu, P. Yuan, G. Shi, X.J. Bao, Chem. Cat. Chem. 5, 2258 (2013)
Z.J. Hu, H.B. Zhang, L. Wang, H.X. Zhang, Y.H. Zhang, H.L. Xu, W. Shen, Y. Tang, Catal. Sci. Technol. 4, 2891 (2014)
J.C. Groen, J.A. Moulijn, J. Perez-Ramirez, J. Mater. Chem. 16, 2121 (2006)
J. Perez-Ramirez, S. Abello, A. Bonilla, J.C. Groen, Adv. Funct. Mater. 19, 164 (2009)
H. Wang, T.J. Pinnavaia, Angew. Chem. Int. Ed. 45, 7603 (2006)
F.S. Xiao, L. Wang, C. Yin, K. Lin, Y. Di, J. Li, R. Xu, D. Su, R. Schlogl, T. Yokoi, T. Tatsumi, Angew. Chem. Int. Ed. 45, 3090 (2006)
B. Zhang, S.A. Davis, S. Mann, Chem. Mater. 14, 1369 (2002)
Y. Liu, W. Zhang, Z. Liu, S. Xu, Y. Wang, Z. Xie, X. Han, X. Bao, J. Phys. Chem. C 112, 15375 (2008)
X. Meng, F.S. Xiao, Chem. Rev. 114, 1521 (2014)
Q. Wu, X. Liu, L. Zhu, L. Ding, P. Gao, X. Wang, S. Pan, C. Bian, X. Meng, J. Xu, F. Deng, S. Maurer, U. Muller, F.S. Xiao, J. Am. Chem. Soc. 137, 1052 (2015)
P. Zhang, L. Wang, L. Ren, L. Zhu, Q. Sun, J. Zhang, X. Meng, F.S. Xiao, J. Mater. Chem. 21, 12026 (2011)
Y. Jin, Q. Sun, G. Qi, C. Yang, J. Xu, F. Chen, X. Meng, F. Deng, F.S. Xiao, Angew. Chem. Int. Ed. Engl. 52, 9172 (2013)
Q. Wu, X. Wang, G. Qi, Q. Guo, S. Pan, X. Meng, J. Xu, F. Deng, F. Fan, Z. Feng, C. Li, S. Maurer, U. Muller, F.S. Xiao, J. Am. Chem. Soc. 136, 4019 (2014)
L. Ren, Q. Wu, C. Yang, L. Zhu, C. Li, P. Zhang, H. Zhang, X. Meng, F.S. Xiao, J. Am. Chem. Soc. 134, 15173 (2012)
S.D. Nagrale, Int. J. Eng. Res. Appl. 2, 1 (2012)
E. Kamseu, L.M. Beleuk à Moungam, M. Cannio, N. Billong, D. Chaysuwan, U. Chinje Melo, C. Leonelli, J. Clean. Prod. 142, 3050 (2017)
S. Chandrasekhar, K.G. Satyanarayana, P.N. Pramada, P. Raghavan, T.N. Gupta, J. Mater. Sci. 38, 3159 (2003)
K. Kordatos, S. Gavela, A. Ntziouni, K.N. Pistiolas, A. Kyritsi, V. Kasselouri-Rigopoulou, Microporous Mesoporous Mater. 115, 189 (2008)
M.K. Naskar, D. Kundu, M. Chatterjee, J. Am. Ceram. Soc. 95, 925 (2012)
K. Kordatos, A. Ntziouni, L. Iliadis, V. Kasselouri-Rigopoulou, J. Mater. Cycles Waste 15, 571 (2013)
K.P. Dey, S. Ghosh, M.K. Naskar, Ceram. Int. 39, 2153 (2013)
Z.G.L.V. Sari, H. Younesi, H. Kazemian, Appl. Nanosci. 5, 737 (2015)
W. Luo, X.Y. Yang, Z.R. Wang, W.F. Huang, J.Y. Chen, W. Jiang, L.J. Wang, X.W. Cheng, Y.H. Deng, D.Y. Zhao, Microporous Mesoporous Mater. 243, 112 (2017)
D. Muller, W. Gessner, H.J. Behrens, G. Scheler, Chem. Phys. Lett. 79, 59 (1981)
D.P. Serrano, J. Aguado, J.M. Escola, J.M. Rodriguez, A. Peral, J. Mater. Chem. 18, 4210 (2008)
S.D. Kim, S.H. Noh, K.H. Seong, W.J. Kim, Microporous Mesoporous Mater. 72, 185 (2004)
T.L. Barr, Zeolites 10, 760 (1990)
W. Choopun, S. Jitkarnka, J. Clean. Prod. 135, 368 (2017)
X.Y. Li, Y. Jiang, X.Q. Liu, L.Y. Shi, D.Y. Zhang, L.B. Sun, ACS Sustain. Chem. Eng. 5, 6124 (2017)
Y. Yu, G. Xiong, C. Li, F.S. Xiao, Microporous Mesoporous Mater. 46, 23 (2001)
Q. Li, B. Mihailova, D. Creaser, J. Sterte, Microporous Mesoporous Mater. 43, 51 (2001)
P.K. Dutta, K.M. Rao, J.Y. Park, J. Phys. Chem. 95, 6654 (1991)
F. Fan, Z. Feng, C. Li, Acc. Chem. Res. 43, 378 (2010)
Y.Y. Yue, H.Y. Liu, P. Yuan, T.S. Li, C.Z. Yu, H. Bi, X.J. Bao, J. Catal. 319, 200 (2014)
J. Perez-Ramirez, D. Verboekend, A. Bonilla, S. Abello, Adv. Funct. Mater. 19, 3972 (2009)
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Zhang, C., Li, S. & Bao, S. A facile and green method for the synthesis of hierarchical ZSM-5 zeolite aggregates from rice husk ash. Res Chem Intermed 44, 3581–3595 (2018). https://doi.org/10.1007/s11164-018-3326-z
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DOI: https://doi.org/10.1007/s11164-018-3326-z