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Preparation of hollow ZSM-11 and its enhanced catalytic properties in the methanol to hydrocarbons reaction

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Abstract

Hollow ZSM-11 was successfully prepared through post-treatment with tetrabutylammonium hydroxide (TBAOH). The products were characterized by XRD, TEM, ICP-OES, 27Al NMR, 27Si NMR, N2 physical adsorption and NH3-TPD and studied as catalysts for the reaction of methanol to hydrocarbons. The characterization results showed that the hollowness might be formed through a dissolution–recrystallization process. The hollow ZSM-11 zeolite showed higher specific surface areas, higher external surface areas, higher mesopore volumes and more acid sites than the untreated ZSM-11, and exhibited excellent catalytic properties in the reaction of methanol to hydrocarbons.

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Acknowledgements

This work has been supported by the National Natural Science Foundation of China (21276183).

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Authors and Affiliations

  1. Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering & Technology, Tianjin University, Tianjin, 300072, People’s Republic of China

    Xiao Wang, Fei Gao, Fanjun Meng, Yaquan Wang, Hengbao Chen, Hongyao Li, Chao Sun, Li Wang, Shuhai Wang, Cui Wang & Xu Zhang

Authors
  1. Xiao Wang
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  2. Fei Gao
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  3. Fanjun Meng
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  4. Yaquan Wang
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  8. Li Wang
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  10. Cui Wang
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  11. Xu Zhang
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Correspondence to Yaquan Wang.

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Wang, X., Gao, F., Meng, F. et al. Preparation of hollow ZSM-11 and its enhanced catalytic properties in the methanol to hydrocarbons reaction. Reac Kinet Mech Cat 122, 1231–1244 (2017). https://doi.org/10.1007/s11144-017-1285-9

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  • DOI: https://doi.org/10.1007/s11144-017-1285-9

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