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A Novel Nano-sized Catalyst CeO2-CuO/Hollow ZSM-5 for NOx Reduction with NH3

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Abstract

Hollow-ZSM-5 was synthesized by a traditional hydrothermal method without alcohol, and a novel na-no-sized Ce-Cu/hollow ZSM-5 sample was prepared by conventional incipient wetness impreganation. The catalysts were characterized by TEM, SEM, XRD, NMR and N2 adsorption-desorption. The results indicate that the hollow-ZSM-5 has a good MFI structure with large surface area. The synthesized CeO2-CuO/hollow ZSM-5 showed an excellent catalytic activity for NOx conversion(90% NOx conversion were obtained) in the temperature range of 340–550 °C under GHSV=480000 mL·g‒1·h‒1 due to its appropriate redox ability and acidity.

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Authors and Affiliations

  1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China

    Ting Yi, Jingwei Li, Yibo Zhang & Xiangguang Yang

  2. University of Chinese Academy of Sciences, Beijing, 100049, P. R. China

    Ting Yi

  3. Jilin Province Key Laboratory of Green Chemistry and Process, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, P. R. China

    Yibo Zhang & Xiangguang Yang

  4. Institute of Carbon Materials Science, Shanxi Datong University, Datong, 037009, P. R. China

    Jingwei Li

Authors
  1. Ting Yi
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  2. Jingwei Li
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  3. Yibo Zhang
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  4. Xiangguang Yang
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Corresponding authors

Correspondence to Yibo Zhang or Xiangguang Yang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21603213, 21677139), the Fund of the Changchun Science and Technology Bureau, China(No.17DY004), the Fund of the Youth Innovation Promotion Association of Chinese Academy of Sciences (No.2018263) and the Development Program of the Science and Technology Department of Jilin Province, China (No.20180201088GX).

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Yi, T., Li, J., Zhang, Y. et al. A Novel Nano-sized Catalyst CeO2-CuO/Hollow ZSM-5 for NOx Reduction with NH3. Chem. Res. Chin. Univ. 34, 661–664 (2018). https://doi.org/10.1007/s40242-018-7333-9

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  • DOI: https://doi.org/10.1007/s40242-018-7333-9

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