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Synthesis, characterization and catalytic activity of neat and alumina supported trans-(diaqua)(N,N-ethylene-bis-salicylamide)chromium(III): a comparative study

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Abstract

A new CrIII–Schiff base complex of N,N′-ethylene-bis-salicylamide (Salm), supported on acidic alumina, was characterized by chemical and spectral (UV–Vis-DRS and FT-IR) analyses. The comparative catalytic activity of the neat and supported metal complex was evaluated using H2O2 decomposition as the model reaction at varying H2O2 concentration and amount of catalyst which showed a higher activity for the supported metal complex. A preliminary study showed that the supported CrIII(Salm) was also active for the oxidation of phenol using H2O2 as oxidant leading to catechol (selectivity ~62%) and hydroquinone (selectivity ~32%) as the major products.

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Authors and Affiliations

  1. P.G. Department of Chemistry, North Orissa University, Takatpur, Baripada, 757 003, Orissa, India

    N. N. Das & P. K. Satapathy

  2. P. G. Department of Chemistry, Utkal University, Bhubaneswar, 751 004, Orissa, India

    S. C. Dash & P. Mohanty

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  1. N. N. Das
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  2. P. K. Satapathy
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  3. S. C. Dash
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  4. P. Mohanty
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Correspondence to N. N. Das.

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Das, N.N., Satapathy, P.K., Dash, S.C. et al. Synthesis, characterization and catalytic activity of neat and alumina supported trans-(diaqua)(N,N-ethylene-bis-salicylamide)chromium(III): a comparative study. Reac Kinet Mech Cat 102, 367–376 (2011). https://doi.org/10.1007/s11144-011-0282-7

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