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Inorganic–Organic Hybrid Materials of Zirconium and Aluminum and Their Usage in the Removal of Methylene Blue

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Abstract

Two novel inorganic–organic hybrid materials, Al-Pydca-3-APDEMS-H and Zr-Pydca-3-APDEMS-H, were prepared by the sol gel method in two steps. In the first step, Al(OsBu)2-Pydca and Zr(OPrn)3-Pydca complexes were prepared from the reactions of aluminum sec-butoxide Al(OsBu)3 and zirconium n-propoxide Zr(OPrn)4 with 2,6-pyridinedicarboxylic acid, respectively. After 3 h of stirring, 3-aminopropyldiethoxymethyl silane (3-APDEMS) and dilute hydrochloric acid were added to the Al(OsBu)2-Pydca and Zr(OPrn)3-Pydca mixtures to hydrolyze the reactions and to form condensation products. These hybrid products were characterized by a combination of Fourier-transform infrared (FT-IR) spectroscopy, powder X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray (EDX) spectroscopy, Brunauer–Emmett–Teller (BET) analysis, Barrett-Joyner-Halenda (BJH) and other analysis methods. These hybrid materials were used for the removal of methylene blue (MB), a cationic organic dye. The removal efficiency of hybrid materials was measured by UV–Vis spectroscopy.

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Acknowledgements

Financial support from the research foundation of Kocaeli University (project No: 2017/107) is gratefully acknowledged.

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Authors and Affiliations

  1. Metallurgical & Materials Engineering Department, Faculty of Chemical and Metallurgical Engineering, Istanbul Technical University, Maslak, Istanbul, 34469, Turkey

    Gizem Özge Kayan

  2. Department of Chemistry, Kocaeli University, Kocaeli, 41380, Turkey

    Asgar Kayan

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  1. Gizem Özge Kayan
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  2. Asgar Kayan
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Correspondence to Asgar Kayan.

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Kayan, G.Ö., Kayan, A. Inorganic–Organic Hybrid Materials of Zirconium and Aluminum and Their Usage in the Removal of Methylene Blue. J Inorg Organomet Polym 31, 3613–3623 (2021). https://doi.org/10.1007/s10904-021-01961-y

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