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Synthesis of New Crystalline Pu(V) Compounds from Solutions: IV. Double Pu(V) Malonates of the Composition Co(NH3)6[PuO2C3H2O4]2A ⋅ nH2O, A = NO3, ClO4, Cl, and Br

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Abstract

New crystalline compounds of the composition Co(NH3)6[PuO2L]2A ⋅ nH2O, where L = C3H2O4 and A = NO3, ClO4, Cl, and Br, were obtained by addition of a small excess of Co(NH3) 3+6 ions to freshly prepared neutral malonate solutions of Pu(V). They are fairly stable in storage in air and isostructural to the corresponding Np(V) compounds. Thermal behavior of the compounds synthesized was studied, and their IR spectra were measured.

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REFERENCES

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia

    N. N. Krot, A. A. Bessonov, I. A. Charushnikova, M. S. Grigor’ev & V. I. Makarenkov

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  1. N. N. Krot
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  2. A. A. Bessonov
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  3. I. A. Charushnikova
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  4. M. S. Grigor’ev
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  5. V. I. Makarenkov
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__________

Translated from Radiokhimiya, Vol. 47, No. 3, 2005, pp. 224–227.

Original Russian Text Copyright © 2005 by Krot, Bessonov, Charushnikova, Grigor’ev, Makarenkov.

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Krot, N.N., Bessonov, A.A., Charushnikova, I.A. et al. Synthesis of New Crystalline Pu(V) Compounds from Solutions: IV. Double Pu(V) Malonates of the Composition Co(NH3)6[PuO2C3H2O4]2A ⋅ nH2O, A = NO3, ClO4, Cl, and Br. Radiochemistry 47, 247–251 (2005). https://doi.org/10.1007/s11137-005-0081-y

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  • DOI: https://doi.org/10.1007/s11137-005-0081-y

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