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Synthesis and structure of U(VI), Np(VI), and Pu(VI) propionates

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Abstract

Crystals of [AnO2(C2H5COO)2(H2O)2], where An = U (I), Np (II), or Pu (III), have been synthesized and studied by X-ray diffraction at 100 K. Compounds I–III are isostructural and crystallize in the monoclinic system, sp. gr. C2/c, Z = 4, with the following unit-cell parameters: a = 7.4677(2), 7.4740(1), 7.512(2) Å, b = 14.2384(4), 14.1681(3), 14.182(4) Å, c = 10.5977(3), 10.5875(2), 10.607(3) Å, β = 92.384(1)°, 92.476(1)°, 92.668(17)°. Crystals I–III are composed of the mononuclear complexes [AnO2(C2H5COO)2(H2O)2] as the main structural units belonging to the crystal-chemical group AB 01 2 M 1 2 (A= AnO2+ 2, B 01 = C2H5COO–, M 1 = H2O). The crystal-chemical analysis of the structures of compounds of the composition UO2 L 2 · nH2O, where L is the carboxylate ion, is performed.

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Authors and Affiliations

  1. Samara State University, ul. Akad. Pavlova 1, Samara, 443011, Russia

    V. N. Serezhkin, A. R. Abdul’myanov & L. B. Serezhkina

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 199071, Russia

    M. S. Grigor’ev & A. M. Fedoseev

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  1. V. N. Serezhkin
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  2. M. S. Grigor’ev
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  3. A. R. Abdul’myanov
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  4. A. M. Fedoseev
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  5. L. B. Serezhkina
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Correspondence to V. N. Serezhkin.

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Original Russian Text © V.N. Serezhkin, M.S. Grigor’ev, A.R. Abdul’myanov, A.M. Fedoseev, L.B. Serezhkina, 2015, published in Kristallografiya, 2015, Vol. 60, No. 6, pp. 906–914.

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Serezhkin, V.N., Grigor’ev, M.S., Abdul’myanov, A.R. et al. Synthesis and structure of U(VI), Np(VI), and Pu(VI) propionates. Crystallogr. Rep. 60, 844–852 (2015). https://doi.org/10.1134/S1063774515050120

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  • DOI: https://doi.org/10.1134/S1063774515050120

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