Abstract
The UL X-ray emission spectra of a wide range of uranium compounds were systematically studied. The chemical and isotope (233, 235, 238U) shifts in the L transitions were estimated. The suitability of these data for identifying the U state in real compounds and minerals was assessed. The experimental results were compared with the theoretical predictions based on the Hartree-Fock-Dirac method.
Similar content being viewed by others
REFERENCES
Domanov, V.P., Buklanov, G.V., and Lobanov, Ju.V., Extended Abstracts, NRC5, 5th Int. Conf. on Nuclear and Radiochemistry, Pontresina (Switzerland), 2000, vol. 1, p. 93.
Soderling, P., Adv. Phys., 1998, vol. 47, no.6, pp. 959–998.
Bersuker, E.B., Effekt Yana-Tellera i vibronnye vzaimodeistviya v sovremennoi khimii (Jahn-Teller Effect and Vibronic Interactions in Modern Chemistry), Moscow: Nauka, 1987.
Ionova, G., Extended Abstracts, NRC5, 5th Int. Conf. on Nuclear and Radiochemistry, Pontresina (Switzerland), 2000, vol. 1, pp. 213–215.
Smirnov, Yu.P., Sumbaev, O.I., Petrovich, E.V., et al., Zh. Eksp. Teor. Fiz., 1969, vol. 57, p. 1139.
Goganov, D.A. and Komyak, N.I., Prib., Sredstva Avtomat. Sist. Upravl. (Moscow), 1981, issue 6b, p. 44.
Kowalski, B.R. and Bender, C.D., J. Am. Chem. Soc., 1973, vol. 95, pp. 686–693.
Barinskii, R.L. and Nefedov, V.D., Rentgenospektral’noe opredelenie zaryadov atomov v molekulakh (X-ray Spectral Determination of Atomic Charges in Molecules), Moscow: Nauka, 1966.
Karaziya, Z.I. et al., Lit. Fiz. Sb., 1974, vol. 15, no.2, pp. 235–247.
Karaziya, Z.I. et al., Lit. Fiz. Sb., 1974, vol. 15, no.2, pp. 249–261.
Sablina, N.O., Cand. Sci. Dissertation, St. Petersburg: Sankt-Peterb. Gos. Univ., 1992.
Makarov, L.L., Extended Abstracts, NRC5, 5th Int. Conf. on Nuclear and Radiochemistry, Pontresina (Switzerland), 2000, vol. 1, pp. 342–345.
Gmelin Handbook of Inorganic Chemistry, Supplement, 1984, vol. C10, pp. 191–225.
Gmelin Handbook of Inorganic Chemistry, Supplement, 1981, vol. C11, p. 78.
Gmelin Handbook of Inorganic Chemistry, Supplement, 1981, vol. C14, p. 86; 1981, vol. C7, pp. 96–140.
Makarov, L.L., Extended Abstracts, NRC5, 5th Int. Conf. on Nuclear and Radiochemistry, Pontresina (Switzerland), 2000, vol. 1, pp. 346–348.
Veal, B.W., Lam, D.J., Carnall, W.T., et al., Phys. Rev. B, 1975, vol. 12, no.12, pp. 5651–5663.
Teterin, Yu.A., Baev, A.S., and Vedrinskii, R.V., Dokl. Akad. Nauk SSSR, 1981, vol. 256, no.2, p. 381.
Grechukhin, D.P., Zhukov, V.I., Zelenkov, A.G., et al., Pis’ma Zh. Eksp. Teor. Fiz., 1980, vol. 31, no.11, p. 627.
Walch, P.F. and Ellis, D.E., J. Chem. Phys., 1976, vol. 65, p. 2387.
Varmusa, K., Pattern Recognition in Chemistry, Springer, 1980, p. 217.
Solomennikov, A.A., Vestn. Sankt-Peterb. Gos. Univ., Ser. 4, 2000, pp. 105–108.
Bratsev, V.F., Deineka, G.V., and Tupitsyn, I.I., Izv. Akad. Nauk SSSR, Ser. Fiz., 1977, vol. 41, p. 2655.
Author information
Authors and Affiliations
Additional information
Translated from Radiokhimiya, Vol. 46, No. 6, 2004, pp. 494–502.
Original Russian Text Copyright © 2004 by Makarov, Solomennikov.
Rights and permissions
About this article
Cite this article
Makarov, L.L., Solomennikov, A.A. “Pattern recognition” from the UL emission spectra as a method for identifying the likeness and difference of uranium state in compounds. Radiochemistry 46, 536–544 (2004). https://doi.org/10.1007/s11137-005-0023-8
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11137-005-0023-8