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Synthesis, structure, and physicochemical properties of compounds Pb(BVUO6)2nH2O (BV = P, As, V)

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Compounds Pb(BVUO6)2nH2O (BV = P, As, V) were synthesized and studied by X-ray diffraction, IR spectroscopy, thermal analysis, and reaction calorimetry. The standard enthalpies and Gibbs energies of formation of the compounds at T = 298 K were determined, and processes involving these compounds were quantitatively characterized.

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REFERENCES

  1. Sidorenko, G.A., Kristallokhimiya mineralov urana (Crystal Chemistry of Uranium Minerals), Moscow: Atomizdat, 1978.

    Google Scholar 

  2. Chernorukov, N.G., Karyakin, N.V., Suleimanov, E.V., and Chernorukov, G.N., Zh. Neorg. Khim., 1994, vol. 39, no.1, pp. 23–26.

    Google Scholar 

  3. Chernorukov, N.G., Karyakin, N.V., Suleimanov, E.V., and Chernorukov, G.N., Radiokhimiya, 1994, vol. 36, no.3, pp. 209–213.

    Google Scholar 

  4. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., and Kharyushina, E.A., Zh. Obshch. Khim., 1992, vol. 62, no.5, pp. 972–974.

    Google Scholar 

  5. JCPDS-ISDD Data File.

  6. Khosrawan-Sazedj, F., Tschermaks Miner. Petr. Mitt., 1982, vol. 29, pp. 193–204.

    Google Scholar 

  7. Miller, S.A. and Taylor, J.C., Z. Kristallogr., 1986, vol. 177, pp. 247–253.

    Google Scholar 

  8. Pushcharovskii, D.Yu., Suleimanov, E.V., Pasero, M., et al., Kristallografiya, 2003, vol. 48, no.2, pp. 246–249.

    Google Scholar 

  9. Borene, J. and Cesbron, F., Bull. Soc. Fr. Miner. Cristallogr., 1971, vol. 94, no.1, pp. 8–14.

    Google Scholar 

  10. Chernorukov, N.G., Suleimanov, E.V., Knyazev, A.V., et al., Zh. Obshch. Khim., 2000, vol. 70, no.9, pp. 1418–1424.

    Google Scholar 

  11. Termicheskie konstanty veshchestv (Thermal Constants of Substances), Glushko, V.P., Ed., Moscow: Nauka, 1965-981, issues 1-10.

    Google Scholar 

  12. Ermilov, S.E., Phase Formation in the Systems AIBVUO6-H2O (AI = Li, Na, K, Rb, Cs; B V = P, As), Cand. Sci. (Chem.) Dissertation, Nizhni Novgorod: Nizhni Novgorod State Univ., 2002.

    Google Scholar 

  13. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., et al., Zh. Obshch. Khim., 1999, vol. 69, no.12, pp. 1944–1947.

    Google Scholar 

  14. Chernorukov, N.G., Suleimanov, E.V., Nipruk, O.V., and Lizunova, G.M., Radiokhimiya, 2001, vol. 43, no.2, pp. 119–124.

    Google Scholar 

  15. Naumov, G.B., Ryzhenko, B.N., and Khodakovskii, I.L., Spravochnik termodinamicheskikh velichin (Handbook of Thermodynamic Quantities), Moscow: Atomizdat, 1971.

    Google Scholar 

  16. Suleimanov, E.V., Karyakin, N.V., Chernorukov, N.G., and Veridusova, V.V., Zh. Fiz. Khim., 2003, vol. 77, no.3, pp. 422–425.

    Google Scholar 

  17. Karyakin, N.V., Chernorukov, N.G., Suleimanov, E.V., et al., Vestn. Nizhegor. Univ., Ser. Khim., 2000, no. 2, pp. 116–126.

  18. Shvarov, Yu.V., Geokhimiya, 1999, vol. 37, no.6, pp. 646–652.

    Google Scholar 

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Translated from Radiokhimiya, Vol. 46, No. 5, 2004, pp. 412–417.

Original Russian Text Copyright © 2004 by Suleimanov, Chernorukov, Golubev.

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Suleimanov, E.V., Chernorukov, N.G. & Golubev, A.V. Synthesis, structure, and physicochemical properties of compounds Pb(BVUO6)2nH2O (BV = P, As, V). Radiochemistry 46, 446–451 (2004). https://doi.org/10.1007/s11137-005-0007-8

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  • DOI: https://doi.org/10.1007/s11137-005-0007-8

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