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Destruction of 2,4-Dichlorophenol Vapor in a Process Involving the Combined Action of DBD in Oxygen and a Catalyst

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Abstract

In this work, the process of decomposition of 2,4-dichlorophenol (2,4-DCP) vapor under the influence of atmospheric pressure DBD in oxygen was studied. The studies were carried out in two modes: with a catalyst (natural vermiculite doped with zirconium) and without it. A number of basic characteristics of the catalyst were assessed. The rates and effective rate constants of sorption processes, as well as decomposition processes in plasma and plasma-catalytic systems, were determined. Based on these data, the energy efficiency of the decomposition process was calculated. The data obtained suggested that the initial stage of decomposition is the reaction of interaction of electrons with pollutant molecules. The catalyst has been shown to speed up the decomposition process, increase energy efficiency and the conversion of 2,4-DCP to CO2 molecules, and prevent the formation of condensed products on the reactor walls. The work estimates the carbon and chlorine balances before and after treatment, which reach a maximum of 99 and 60%, respectively. It was also shown that the catalyst retains its activity for at least 7 h of continuous operation.

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All data generated or analyzed during this study are included in this published article in results section.

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Acknowledgements

The work was supported by the Ministry of Higher Education and Science of the Russian Federation, project no. FZZW-2023-0010 using facilities of the Center for Shared Use of Scientific Equipment at the Ivanovo State University of Chemistry and Technology (with the support of the Ministry of Higher Education and Science of Russia, agreement no. 075-15-2021-671).

Funding

The work was supported by the Ministry of Higher Education and Science of the Russian Federation, project no. FZZW-2023-0010.

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Authors and Affiliations

  1. Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Sheremetiev Ave., 7, Ivanovo, Russia, 153000

    K. A. Lapshova, E. Yu. Kvitkova, T. V. Izvekova, V. I. Grinevich, G. I. Gusev & A. A. Gushchin

  2. Department of Technology of Inorganic Substance, Ivanovo State University of Chemistry and Technology, Sheremetiev Ave., 7, Ivanovo, Russia, 153000

    N. E. Gordina

  3. Department of Microelectronic Devices and Materials, Ivanovo State University of Chemistry and Technology, Sheremetiev Ave., 7, Ivanovo, Russia, 153000

    V. V. Rybkin

Authors
  1. K. A. Lapshova
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  2. N. E. Gordina
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  3. E. Yu. Kvitkova
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  4. T. V. Izvekova
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  5. V. I. Grinevich
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  7. V. V. Rybkin
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  8. A. A. Gushchin
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Contributions

All authors contributed to the writing of this study. Data collection and analysis were performed by K.A. Lapshova, G.I. Gusev and E.Yu. Kvitkova. A.A. Gushchin, V.V. Rybkin and V.V. Grinevich wrote background and discussion parts, made calculations and drawing figures and tables. T.V. Izvekova and N.E. Gordina were responsible for the designing and literature search. The first draft of the manuscript was written by V.V. Grinevich. A.A. Gushchin along with the other authors reviewed and edited all versions of the manuscript. A.A. Gushchin was also responsible for project administration and supervision. All authors read and approved the final manuscript.

Corresponding author

Correspondence to E. Yu. Kvitkova.

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Lapshova, K.A., Gordina, N.E., Kvitkova, E.Y. et al. Destruction of 2,4-Dichlorophenol Vapor in a Process Involving the Combined Action of DBD in Oxygen and a Catalyst. Plasma Chem Plasma Process 44, 853–865 (2024). https://doi.org/10.1007/s11090-024-10462-y

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