Skip to main content

Advertisement

SpringerLink
Log in

Destruction of 2,4-Dichlorophenol in Water Solution Using a Combined Process of Sorption and Plasma Exposure to DBD

  • Original Paper
  • Published:
Plasma Chemistry and Plasma Processing Aims and scope Submit manuscript

Abstract

The results of studies of the decomposition of 2,4-dichlorophenol (2,4-DCP) in its aqueous solution under the action of atmospheric pressure DBD in an oxygen flow are presented. A new reactor design was used in which the discharge zone was filled with a sorbent (diatomite). It was found that the kinetics of decomposition obeys a first-order kinetic equation for the concentration of 2,4-DCP. The presence of an adsorbent significantly improves the parameters of the decomposition process. Decomposition rates, rate constants and energy efficiency are doubled. So, at a specific discharge power of 1.8 W/cm3 in the presence of a sorbent, the rate constant was ~1 s−1, and without it, ~0.5 s−1. The energy efficiency was 0.031 and 0.016 molecules per 100 eV, respectively. The parameters of the treated solution are improved in terms of its potential toxicity. The concentrations of the main decomposition products (aldehydes, carboxylic acids) in the presence of a sorbent are significantly less than without it. This is due to an increase in the rate of conversion of these products into carbon dioxide molecules. It was also shown that the decomposition of one 2,4-DCP molecule leads to the formation of two chloride ions in solution, and the ozone formed in the discharge does not significantly affect the destruction process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Hoseini SN, Pirzaman AK, Aroon MA, Pirbazari AE (2017) Photocatalytic degradation of 2,4-dichlorophenol by Co-doped TiO2 (Co/TiO2) nanoparticles and Co/TiO2 containing mixed matrix membranes. J Water Process Eng 17:124–134

    Article  Google Scholar 

  2. Zhang C, Zhou M, Ren G, Yu X, Ma L, Yang J, Yu F (2015) Heterogeneous electro-Fenton using modified iron–carbon as catalyst for 2,4-dichlorophenol degradation: influence factors, mechanism and degradation pathway. Water Res 70:414–424

    Article  CAS  Google Scholar 

  3. Jiang G, Lan M, Zhang Z, Lv X, Lou Z, Xu X, Dong F, Zhang S (2017) Identification of active hydrogen species on palladium nanoparticles for an enhanced electrocatalytic hydrodechlorination of 2,4-dichlorophenol in water. Environ Sci Technol 51(13):7599–7605

    Article  CAS  Google Scholar 

  4. Simsek EB, Aytas B, Duranoglu D, Beker U, Trochimczuk AW (2016) A comparative study of 2-chlorophenol, 2,4-dichlorophenol, and 2,4,6-trichlorophenol adsorption onto polymeric, commercial, and carbonaceous adsorbents. Desalination Water Treat 57(21):9940–9956

    Article  Google Scholar 

  5. Zhang H, Zhang Q, Miao C, Huang Q (2018) Degradation of 2,4-dichlorophenol in aqueous solution by dielectric barrier discharge: effects of plasma-working gases, degradation pathways and toxicity assessment. Chemosphere 204:351–358

    Article  CAS  Google Scholar 

  6. Aziz KHH, Miessner H, Mueller S, Mahyar A, Kalass D, Moeller D, Khorshid I, Rashid MAM (2018) Comparative study on 2,4-dichlorophenoxyacetic acid and 2,4-dichlorophenol removal from aqueous solutions via ozonation, photocatalysis and non-thermal plasma using a planar falling film reactor. J Hazard Mater 343:107–115

    Article  Google Scholar 

  7. Yang H, Caixia S, Tezuka M (2013) Plasma-induced decomposition of dichlorophenols and trichlorophenols in water by means of anodic contact glow discharge electrolysis. Plasma Chem Plasma Process 33(6):1043–1052

    Article  CAS  Google Scholar 

  8. Gushchin AA, Grinevich VI, Kozlov AA, Kvitkova EY, Shutov DA, Rybkin VV (2017) Destruction of 2,4-dichlorophenol in an atmospheric pressure dielectric darrier discharge in oxygen. Plasma Chem Plasma Process 37(5):1331–1341

    Article  CAS  Google Scholar 

  9. Bobkova ES, Rybkin VV (2015) Peculiarities of energy efficiency comparison of plasma chemical reactors for water purification from organic substances. Plasma Chem Plasma Process 35(1):133–142

    Article  CAS  Google Scholar 

  10. Hao XL, Zhou MH, Zhang Y, Lei LC (2006) Enhanced degradation of organic pollutant 4-chlorophenol in water by non-thermal plasma process with TiO2. Plasma Chem Plasma Process 26(5):455–468

    Article  CAS  Google Scholar 

  11. Qu GZ, Lu N, Li J, Wu Y, Li GF, Li D (2009) Simulataneous pentachlorophenol decomposition and granular activated carbon regeneration assisted by dielectric barrier discharge plasma. J Hazard Mater 172(1):472–478

    Article  CAS  Google Scholar 

  12. Gushchin AA, Grinevich VI, Gusev GI, Kvitkova EY, Rybkin VV (2018) Removal of oil products from water using a combined process of sorption and plasma exposure to DBD. Plasma Chem Plasma Process 38(5):1021–1033

    Article  CAS  Google Scholar 

  13. State Standard of RF 51209-98 (1998) Drinking water. Method for determining the content of organochlorine pesticides by gas-liquid chromatography, Ministry of Health of Russia (in Russian)

  14. Simonov V, Nekhorosheva E, Zavorovskaya N (1988) Analysis of the air during the processing of polymeric materials. Khimiya, Moscow

    Google Scholar 

  15. Parkinson WH, Yoshino K, Freeman DE (1988) Absolute absorption cross section measurements of ozone and the temperature dependence at four reference wavelengths leading to renormalization of the cross section between 240 and 350 nm. Smithsonian Institution Astrophysical Observatory, Cambridge, p 02138

    Google Scholar 

  16. Bobkova ES, Khodor YaV, Kornilova ON, Rybkin VV (2014) Chemical composition of plasma of dielectric barrier discharge at atmospheric pressure with a liquid electrode. High Temp 52(4):511–517

    Article  CAS  Google Scholar 

  17. Gushchin AA, Grinevich VI, Shulyk VYa, Kvitkova EYu, Rybkin VV (2018) Destruction kinetics of 2,4-dichlorophenol aqueous solutions in an atmospheric pressure dielectric barrier discharge in oxygen. Plasma Chem Plasma Process 38(1):123–134

    Article  CAS  Google Scholar 

  18. Kovačević VV, Dojčinović DP, Jović M, Roglić GM, Obradović BM, Kuraica MM (2017) Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres. J Phys D Appl Phys 50(15):155205

    Article  Google Scholar 

  19. Kogelschatz U (2003) Dielectric-barrier discharges: their history, discharge physics, and industrial applications. Plasma Chem Plasma Process 23(1):1–46

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This study was carried out in the frame of State Assignment of the Ministry of Education and Science of the RF, No. FZZW-2020-0009 and No. FZZW-2020-0010 and it was supported by the RFBR Grant, Project No. 18-08-01239 A.

Author information

Authors and Affiliations

  1. Department of Industrial Ecology, Ivanovo State University of Chemistry and Technology, Sheremetiev ave., 7, Ivanovo, 153000, Russia

    Andreiy A. Gushchin, Grigoriy I. Gusev, Vladimir I. Grinevich, Tatiana V. Izvekova & Elena Yu. Kvitkova

  2. Department of Microelectronic Devices and Materials, Ivanovo State University of Chemistry and Technology, Sheremetiev ave., 7, Ivanovo, 153000, Russia

    Vladimir V. Rybkin

Authors
  1. Andreiy A. Gushchin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Grigoriy I. Gusev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Vladimir I. Grinevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Tatiana V. Izvekova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Elena Yu. Kvitkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Vladimir V. Rybkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Vladimir V. Rybkin.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gushchin, A.A., Gusev, G.I., Grinevich, V.I. et al. Destruction of 2,4-Dichlorophenol in Water Solution Using a Combined Process of Sorption and Plasma Exposure to DBD. Plasma Chem Plasma Process 41, 421–431 (2021). https://doi.org/10.1007/s11090-020-10132-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11090-020-10132-9

Keywords

Search

Navigation