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Comparative Isothermal Oxidation Resistance of Selected Single-Crystal Ni-Based Superalloys With and Without Pt-Modified Surface Layers

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Abstract

Isothermal oxidation tests at 1150 °C show that the commercial grade of the single-crystal Ni-based superalloy CMSX-4 is superior to that of the CMSX-10 version. Superalloy CMSX-4 is observed to undergo a shorter stage of transient oxidation and to be able to form more protective oxides during the earlier stages of the reaction as compared to superalloy CMSX-10. This behavior is correlated with the difference in chemical composition between the two superalloys. A significant improvement in oxidation resistance of both superalloys is realized after diffusing a 10 μm thick layer of Pt into their surfaces to produce a Pt-rich surface layer of γ′-phase. However, the oxidation resistance of the composite Pt/CMSX-10 system becomes superior to that of the Pt/CMSX-4 system. Most evidence indicates that this is a reflection of the higher microstructural stability of the γ′-phase in superalloy CMSX-10 and the added beneficial effect provided by Pt.

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Acknowledgements

It is a pleasure to acknowledge the continued support provided by King Fahd University of Petroleum and Minerals as well as the Center for Engineering Research.

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  1. Center for Engineering Research, Research Institute, King Fahd University of Petroleum and Minerals, Box 1639, Dhahran, 31261, Saudi Arabia

    H. M. Tawancy

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Tawancy, H.M. Comparative Isothermal Oxidation Resistance of Selected Single-Crystal Ni-Based Superalloys With and Without Pt-Modified Surface Layers. Oxid Met 93, 371–386 (2020). https://doi.org/10.1007/s11085-020-09960-z

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  • DOI: https://doi.org/10.1007/s11085-020-09960-z

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