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Slow Transition from Protective to Breakaway Oxidation of Haynes 214 Foil at High Temperature

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Abstract

The oxidation behaviour of thin sheet specimens of the alumina forming nickel base alloy 214 in the temperature range 1,100–1,200 °C is described. Rapid transient oxidation produces a spinel oxide layer which then stops growing, as a protective alumina layer forms beneath. The slow growth of this alumina ceases when the alloy aluminium content is exhausted. Subsequent formation of an innermost chromia layer signals an increase in oxygen activity at the scale-alloy interface. The abnormally slow growth of this layer extends the alloy lifetime. Examination of individual layer growth processes revealed a complex time dependence of spinel composition as a result of Cr evaporation, and dissolution of alumina in the innermost chromia.

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Acknowledgments

Mr. Cosler and Ms. A. Kick are kindly acknowledged for carrying out high temperature exposures and TG-analyses, Mr. M. Ziegner for XRD measurements, Mr. J. Bartsch and Mr. V. Gutzeit for metallographic preparation. The authors are grateful to Mr. M. Borzikov for carrying out SNMS analyses.

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Authors and Affiliations

  1. School of Materials Science and Engineering, The University of New South Wales, Sydney, NSW, 2052, Australia

    D. J. Young

  2. Forschungszentrum Jülich GmbH, IEK-2, 52425, Julich, Germany

    A. Chyrkin, J. He, D. Grüner & W. J. Quadakkers

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  1. D. J. Young
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  2. A. Chyrkin
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  3. J. He
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  4. D. Grüner
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  5. W. J. Quadakkers
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Correspondence to A. Chyrkin.

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J. He was formerly with Forschungszentrum Jülich GmbH.

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Young, D.J., Chyrkin, A., He, J. et al. Slow Transition from Protective to Breakaway Oxidation of Haynes 214 Foil at High Temperature. Oxid Met 79, 405–427 (2013). https://doi.org/10.1007/s11085-013-9364-4

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  • DOI: https://doi.org/10.1007/s11085-013-9364-4

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