Abstract
The corrosion of metals at high temperatures in halogen containing environments differs from most other types of high temperature corrosion in that in addition to solid and liquid corrosion products volatile phases are also formed. The latter are not covered by the usual thermodynamic stability diagrams, which are often used for prediction of the corrosion products formed, and indirectly on whether corrosion has to be regarded as critical or not. The present paper aims at including the situation where gas phase corrosion products determine the extent of corrosion and a new type of diagram is developed and discussed for the example of chlorine containing environments. Part I of this paper (Latreche et al. Oxid Met 2009) was dedicated to the establishment of the basis for a new extended approach to a corrosion risk assessment diagram called the “dynamic” quasi-stability diagram. The present part deals with the principles of the new type of diagram and the establishment of specific diagrams for the most common alloying elements, i.e. Fe, Ni, Mo, Cr, Si, Al. For the development of the specific diagrams, the calculation of gas viscosities and gas diffusion coefficients of all relevant volatile potential corrosion products was conducted, with methods specified in the paper. The new “dynamic” quasi-stability diagrams were then compared to experimental results from kinetics investigations of pure metals, which showed quite good agreement with the experimental observations. Furthermore, the diagrams were used to assess the behaviour of the metallic elements in alloys. Again, in this case good agreement between prediction and experimental results was observed if the specific role of the different elements in the corrosion behaviour of the alloys was taken into account.
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References
H. Latreche, S. Doublet, and M. Schütze, Oxidation of Metals (2009). doi:10.1007/s11085-009-9147-0.
S. Doublet, PhD thesis (RWTH Aachen, Germany, 2006).
R. J. Fruehan and L. J. Martonik, Metallurgical Transactions 4, 2793 (1973).
Y. S. Touloukian, S. C. Saxena, and P. Hestermans, Thermophysical Properties of Matter, Vol. 11: Viscosity (IFI/Plenum, New York, 1970).
S. Angus and B. Armstrong, International Thermodynamic Tables of the Fluid State (Argon, Butterworths, London, 1971).
Gas Encyclopedia, L’Air Liquide Scientific Division (Elsevier, 1976), p. 1084.
T.-H. Chung, L. L. Lee, and K. E. Starling, Industrial and Engineering Chemistry Fundamentals 23, 8 (1984).
T.-H. Chung, M. Ajlan, L. L. Lee, and K. E. Starling, Industrial and Engineering Chemistry Research 27, 671 (1988).
B. E. Poling, J. M. Prausnitz, and J. P. O’Connell, The Properties of Gases and Liquids, 5th edn (McGraw-Hill, New York, 2001).
P. D. Neufeld, A. R. Janzen, and R. A. Aziz, Journal of Chemical Physics 57, 1100 (1972).
D. Reichenberg, “The Viscosities of Gas Mixtures at Moderate Pressures”, NPL Report Chem, Vol. 29 (National Physical Laboratory, Teddington, England, 1974).
D. Reichenberg, New Simplified Methods for the Estimation of the Viscosities of Gas Mixtures at Moderate Pressures, Nat. Eng. Lab. Rept. Chem, Vol. 53 (East Kilbride, Glasgow, Scotland, 1977).
D. Reichenberg, Symposium on Transports Properties of Fluids and Fluid Mixtures, Natl. Eng. Lab (East Kilbride, Glasgow, Scotland, 1979).
S. Doublet, Doctoral Thesis (RTWH Aachen, 2006).
R. J. Fruehan, Metallurgical Transactions 3, 2585 (1972).
M. J. McNallan and W. W. Liang, Journal of the American Ceramic Society 64, 302 (1981).
Y. Y. Lee and M. J. McNallan, Metallurgical Transactions 18A, 1099 (1987).
K. Reinhold and K. Hauffe, Journal of the Electrochemical Society 6, 877 (1977).
R. J. Fruehan, Metallurgical Transactions 3, 2586 (1972).
A. Landsberg and F. E. Block, Report of Investigations 6649 (US Department of the Interior Bureau of Mines, 1965).
A. Landsberg, C. L. Hoatson, and F. E. Block, Journal of Electrochemical Society 118, 1331 (1971).
H. Latreche, G. Tegeder, T. Weber, G. Wolf, P. Masset, and M. Schütze, Eurocorr 2007 (Freiburg im Breisgau, 2007), pp. 10.9.–13.9.
K. Hauffe and J. Hinrichs, Materials and Corrosion 11, 954 (1970).
Y. Y. Lee and M. J. McNallan, Metallurgical Transactions A18, 1099 (1987).
C. Schwalm and M. Schütze, Materials and Corrosion 51, 34 (2000).
C. Schwalm and M. Schütze, Materials and Corrosion 51, 73 (2000).
R. Bender and M. Schütze, Materials and Corrosion 54, 652 (2003).
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The financial support of the Bundesministerium für Wirtschaft und Technologie (BMWi) via the Arbeitsgemeinschaft industrieller Forschungsvereinigungen (AiF) under Contract AiF No. 13266N is gratefully acknowledged.
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Latreche, H., Doublet, S. & Schütze, M. Development of Corrosion Assessment Diagrams for High Temperature Chlorine Corrosion Part II: Development of “Dynamic” Quasi-stability Diagrams. Oxid Met 72, 31–65 (2009). https://doi.org/10.1007/s11085-009-9146-1
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DOI: https://doi.org/10.1007/s11085-009-9146-1